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Line Broadening in Field Metal-Poor Red Giant and Red Horizontal Branch Stars
We report 349 radial velocities for 45 metal-poor field red giant branch(RGB) and red horizontal branch (RHB) stars, with time coverage rangingfrom 1 to 21 years. We have identified one new spectroscopic binary, HD4306, and one possible such system, HD 184711. We also provide 57 radialvelocities for 11 of the 91 stars reported in our previous work. All butone of the 11 stars had been found to have variable radial velocities.New velocities for the long-period spectroscopic binaries BD-1 2582 andHD 108317 have extended the time coverage to 21.7 and 12.5 years,respectively, but in neither case have we yet completed a full orbitalperiod. As was found in the previous study, radial velocity "jitter" ispresent in many of the most luminous stars. Excluding stars showingspectroscopic binary orbital motion, all 7 of the red giants withestimated MV values more luminous than -2.0 display jitter,as well as 3 of the 14 stars with -2.0 < MV <= -1.4. Wehave also measured the line broadening in all the new spectra, usingsynthetic spectra as templates. Comparison with results fromhigh-resolution and higher signal-to-noise (S/N) spectra employed byother workers shows good agreement down to line-broadening levels of 3km s-1, well below our instrumental resolution of 8.5 kms-1. As the previous work demonstrated, the majority of themost luminous red giants show significant line broadening, as do many ofthe red horizontal branch stars, and we briefly discuss possible causes.The line broadening appears related to velocity jitter, in that bothappear primarily among the highest luminosity red giants.

Strömgren Photometry of Galactic Globular Clusters. I. New Calibrations of the Metallicity Index
We present a new calibration of the Strömgren metallicity indexm1 using red giant (RG) stars in four globular clusters (GCs:M92, M13, NGC 1851, 47 Tuc) with metallicity ranging from -2.2 to -0.7,marginally affected by reddening [E(B-V)<=0.04] and with accurate(u,v,b,y) photometry. The main difference between the newmetallicity-index-color (MIC) relations and similar relations availablein the literature is that we have adopted the u-y and v-y colors insteadof b-y. These colors present a stronger sensitivity to effectivetemperature, and the MIC relations show a linear slope. The differencebetween photometric estimates and spectroscopic measurements for RGs inM71, NGC 288, NGC 362, NGC 6397, and NGC 6752 is 0.04+/-0.03 dex(σ=0.11 dex). We also apply the new MIC relations to 85 field RGswith metallicity ranging from -2.4 to -0.5 and accurate reddeningestimates. We find that the difference between photometric estimates andspectroscopic measurements is -0.14+/-0.01 dex (σ=0.17 dex). Wealso provide two sets of MIC relations based on evolutionary models thathave been transformed into the observational plane by adopting eithersemiempirical or theoretical color-temperature relations. We apply thesemiempirical relations to the nine GCs and find that the differencebetween photometric and spectroscopic metallicities is 0.04+/-0.03 dex(σ=0.10 dex). A similar agreement is found for the sample of fieldRGs, with a difference of -0.09+/-0.03 dex (with σ=0.19 dex). Thedifference between metallicity estimates based on theoretical relationsand spectroscopic measurements is -0.11+/-0.03 dex (σ=0.14 dex)for the nine GCs and -0.24+/-0.03 dex (σ=0.15 dex) for the fieldRGs. Current evidence indicates that new MIC relations providemetallicities with an intrinsic accuracy better than 0.2 dex.Based in part on observations collected with the 1.54 m Danish Telescopeoperated at ESO (La Silla, Chile) and with the Nordic Optical Telescope(NOT) operated at La Palma (Spain).

Halo Star Streams in the Solar Neighborhood
We have assembled a sample of halo stars in the solar neighborhood tolook for halo substructure in velocity and angular momentum space. Oursample (231 stars) includes red giants, RR Lyrae variable stars, and redhorizontal branch stars within 2.5 kpc of the Sun with [Fe/H] less than-1.0. It was chosen to include stars with accurate distances, spacevelocities, and metallicities, as well as well-quantified errors. Withour data set, we confirm the existence of the streams found by Helmi andcoworkers, which we refer to as the H99 streams. These streams have adouble-peaked velocity distribution in the z-direction (out of theGalactic plane). We use the results of modeling of the H99 streams byHelmi and collaborators to test how one might use vz velocityinformation and radial velocity information to detect kinematicsubstructure in the halo. We find that detecting the H99 streams withradial velocities alone would require a large sample (e.g.,approximately 150 stars within 2 kpc of the Sun and within 20° ofthe Galactic poles). In addition, we use the velocity distribution ofthe H99 streams to estimate their age. From our model of the progenitorof the H99 streams, we determine that it was accreted between 6 and 9Gyr ago. The H99 streams have [α/Fe] abundances similar to otherhalo stars in the solar neighborhood, suggesting that the gas thatformed these stars were enriched mostly by Type II supernovae. We havealso discovered in angular momentum space two other possiblesubstructures, which we refer to as the retrograde and progradeoutliers. The retrograde outliers are likely to be halo substructure,but the prograde outliers are most likely part of the smooth halo. Theretrograde outliers have significant structure in the vφdirection and show a range of [α/Fe], with two having low[α/Fe] for their [Fe/H]. The fraction of substructure stars in oursample is between 5% and 7%. The methods presented in this paper can beused to exploit the kinematic information present in future largedatabases like RAVE, SDSS-II/SEGUE, and Gaia.

Measuring the Balmer Jump and the Effective Gravity in FGK Stars
It is difficult to accurately measure the effective gravity (logg) inlate-type stars using broadband (e.g., UBV or SDSS) or intermediate-band(uvby) photometric systems, especially when the stars can cover a rangeof metallicities and reddenings. However, simple spectroscopicobservational and data reduction techniques can yield accurate valuesfor logg through comparison of the Balmer jumps of low-resolutionspectra with recent grids of synthetic flux spectra.

The Hamburg/ESO R-process enhanced star survey (HERES). III. HE 0338-3945 and the formation of the r + s stars
We have derived abundances of 33 elements and upper limits for 6additional elements for the metal-poor ([Fe/H] = -2.42) turn-off star HE0338-3945 from high-quality VLT-UVES spectra. The star is heavilyenriched, by about a factor of 100 relative to iron and the Sun, in theheavy s-elements (Ba, La, ...). It is also heavily enriched in Eu, whichis generally considered an r-element, and in other similar elements. Itis less enriched, by about a factor of 10, in the lighter s-elements(Sr, Y and Zr). C is also strongly enhanced and, to a somewhat lesserdegree, N and O. These abundance estimates are subject to severeuncertainties due to NLTE and thermal inhomogeneities which are nottaken into detailed consideration. However, an interesting result, whichis most probably robust in spite of these uncertainties, emerges: theabundances derived for this star are very similar to those of otherstars with an overall enhancement of all elements beyond the iron peak.We have defined criteria for this class of stars, r+s stars, and discussnine different scenarios to explain their origin. None of theseexplanations is found to be entirely convincing. The most plausiblehypotheses involve a binary system in which the primary component goesthrough its giant branch and asymptotic giant branch phases and producesCNO and s-elements which are dumped onto the observed star. Whether ther-element Eu is produced by supernovae before the star was formed(perhaps triggering the formation of a low-mass binary), by a companionas it explodes as a supernova (possibly triggered by mass transfer), orwhether it is possibly produced in a high-neutron-density version of thes-process is still unclear. Several suggestions are made on how toclarify this situation.

Oxygen abundances in metal-poor subgiants as determined from [O I], O I and OH lines
The debate on the oxygen abundances of metal-poor stars has its originin contradictory results obtained using different abundance indicators.To achieve a better understanding of the problem we have acquired highquality spectra with the Ultraviolet and Visual Echelle Spectrograph atVLT, with a signal-to-noise of the order of 100 in the near ultravioletand 500 in the optical and near infrared wavelength range. Threedifferent oxygen abundance indicators, OH ultraviolet lines around 310.0nm, the [O i] line at 630.03 nm and the O i lines at 777.1-5 nm wereobserved in the spectra of 13 metal-poor subgiants with-3.0≤[Fe/H]≤-1.5. Oxygen abundances were obtained from theanalysis of these indicators which was carried out assuming localthermodynamic equilibrium and plane-parallel model atmospheres.Abundances derived from O i were corrected for departures from localthermodynamic equilibrium. Stellar parameters were computed usingT_eff-vs.-color calibrations based on the infrared flux method andBalmer line profiles, Hipparcos parallaxes and Fe II lines. [O/Fe]values derived from the forbidden line at 630.03 nm are consistent withan oxygen/iron ratio that varies linearly with [Fe/H] as[O/Fe]=-0.09(±0.08)[Fe/H]+0.36(±0.15). Values based on theO i triplet are on average 0.19±0.22 dex(s.d.) higher than thevalues based on the forbidden line while the agreement between OHultraviolet lines and the forbidden line is much better with a meandifference of the order of -0.09±0.25 dex(s.d.). In general, ourresults follow the same trend as previously published results with theexception of the ones based on OH ultraviolet lines. In that case ourresults lie below the values which gave rise to the oxygen abundancedebate for metal-poor stars.

Li and Be depletion in metal-poor subgiants
A sample of metal-poor subgiants has been observed with the UVESspectrograph at the Very Large Telescope and abundances of Li and Behave been determined. Typical signal-to-noise per spectral bin valuesfor the co-added spectra are of the order of 500 for the ion{Li}{i} line(670.78 nm) and 100 for the ion{Be}{ii} doublet lines (313.04 nm). Thespectral analysis of the observations was carried out using the Uppsalasuite of codes and marcs (1D-LTE) model atmospheres with stellarparameters from photometry, parallaxes, isochrones and Fe ii lines.Abundance estimates of the light elements were corrected for departuresfrom local thermodynamic equilibrium in the line formation. Effectivetemperatures and Li abundances seem to be correlated and Be abundancescorrelate with [O/H]. Standard models predict Li and Be abundancesapproximately one order of magnitude lower than main-sequence valueswhich is in general agreement with the observations. On average, ourobserved depletions seem to be 0.1 dex smaller and between 0.2 and 0.4dex larger (depending on which reference is taken) than those predictedfor Li and Be, respectively. This is not surprising since the initial Liabundance, as derived from main-sequence stars on the Spite plateau, maybe systematically in error by 0.1 dex or more, and uncertainties in thespectrum normalisation and continuum drawing may affect our Beabundances systematically.

Galactic model parameters for field giants separated from field dwarfs by their 2MASS and V apparent magnitudes
We present a method which separates field dwarfs and field giants bytheir 2MASS and V apparent magnitudes. This method is based onspectroscopically selected standards and is hence reliable. We appliedit to stars in two fields, SA 54 and SA 82, and we estimated a full setof Galactic model parameters for giants including their total localspace density. Our results are in agreement with the ones given in therecent literature.

uvby-β photometry of high-velocity and metal-poor stars. XI. Ages of halo and old disk stars
New uvby-β data are provided for 442 high-velocity and metal-poorstars; 90 of these stars have been observed previously by us, and 352are new. When combined with our previous two photometric catalogues, thedata base is now made up of 1533 high-velocity and metal-poor stars, allwith uvby-β photometry and complete kinematic data, such as propermotions and radial velocities taken from the literature. Hipparcos, plusa new photometric calibration for Mv also based on theHipparcos parallaxes, provide distances for nearly all of these stars;our previous photometric calibrations give values for E(b-y) and [Fe/H].The [Fe/H], V(rot) diagram allows us to separate these stars intodifferent Galactic stellar population groups, such as old-thin-disk,thick-disk, and halo. The X histogram, where X is our stellar-populationdiscriminator combining V(rot) and [Fe/H], and contour plots for the[Fe/H], V(rot) diagram both indicate two probable components to thethick disk. These population groups and Galactic components are studiedin the (b-y)0, Mv diagram, compared to theisochrones of Bergbusch & VandenBerg (2001, ApJ, 556, 322), toderive stellar ages. The two thick-disk groups have the meancharacteristics: ([Fe/H], V(rot), Age, σW') ≈ (-0.7dex, 120 km s-1, 12.5 Gyr, 62.0 km s-1), and≈(-0.4, 160, 10.0, 45.8). The seven most metal-poor halo groups,-2.31 ≤ [Fe/H] ≤ -1.31, show a mean age of 13.0 ± 0.2(mean error) Gyr, giving a mean difference from the WMAP results for theage of the Universe of 0.7 ± 0.3 Gyr. These results for the agesand components of the thick disk and for the age of the Galactic halofield stars are discussed in terms of various models and ideas for theformation of galaxies and their stellar populations.

Pulkovo compilation of radial velocities for 35495 stars in a common system.
Not Available

Estimation of Carbon Abundances in Metal-Poor Stars. I. Application to the Strong G-Band Stars of Beers, Preston, and Shectman
We develop and test a method for the estimation of metallicities([Fe/H]) and carbon abundance ratios ([C/Fe]) for carbon-enhancedmetal-poor (CEMP) stars based on the application of artificial neuralnetworks, regressions, and synthesis models to medium-resolution (1-2Å) spectra and J-K colors. We calibrate this method by comparisonwith metallicities and carbon abundance determinations for 118 starswith available high-resolution analyses reported in the recentliterature. The neural network and regression approaches make use of apreviously defined set of line-strength indices quantifying the strengthof the Ca II K line and the CH G band, in conjunction with J-K colorsfrom the Two Micron All Sky Survey Point Source Catalog. The use ofnear-IR colors, as opposed to broadband B-V colors, is required becauseof the potentially large affect of strong molecular carbon bands onbluer color indices. We also explore the practicality of obtainingestimates of carbon abundances for metal-poor stars from the spectralinformation alone, i.e., without the additional information provided byphotometry, as many future samples of CEMP stars may lack such data. Wefind that although photometric information is required for theestimation of [Fe/H], it provides little improvement in our derivedestimates of [C/Fe], and hence, estimates of carbon-to-iron ratios basedsolely on line indices appear sufficiently accurate for most purposes.Although we find that the spectral synthesis approach yields the mostaccurate estimates of [C/Fe], in particular for the stars with thestrongest molecular bands, it is only marginally better than is obtainedfrom the line index approaches. Using these methods we are able toreproduce the previously measured [Fe/H] and [C/Fe] determinations withan accuracy of ~0.25 dex for stars in the metallicity interval-5.5<=[Fe/H]<=-1.0 and with 0.2<=(J-K)0<=0.8. Athigher metallicity, the Ca II K line begins to saturate, especially forthe cool stars in our program, and hence, this approach is not useful insome cases. As a first application, we estimate the abundances of [Fe/H]and [C/Fe] for the 56 stars identified as possibly carbon-rich, relativeto stars of similar metal abundance, in the sample of ``strong G-band''stars discussed by Beers, Preston, and Shectman.

The lithium content of the Galactic Halo stars
Thanks to the accurate determination of the baryon density of theuniverse by the recent cosmic microwave background experiments, updatedpredictions of the standard model of Big Bang nucleosynthesis now yieldthe initial abundance of the primordial light elements withunprecedented precision. In the case of ^7Li, the CMB+SBBN value issignificantly higher than the generally reported abundances for Pop IIstars along the so-called Spite plateau. In view of the crucialimportance of this disagreement, which has cosmological, galactic andstellar implications, we decided to tackle the most critical issues ofthe problem by revisiting a large sample of literature Li data in halostars that we assembled following some strict selection criteria on thequality of the original analyses. In the first part of the paper wefocus on the systematic uncertainties affecting the determination of theLi abundances, one of our main goal being to look for the "highestobservational accuracy achievable" for one of the largest sets of Liabundances ever assembled. We explore in great detail the temperaturescale issue with a special emphasis on reddening. We derive four sets ofeffective temperatures by applying the same colour {T}_eff calibrationbut making four different assumptions about reddening and determine theLTE lithium values for each of them. We compute the NLTE corrections andapply them to the LTE lithium abundances. We then focus on our "best"(i.e. most consistent) set of temperatures in order to discuss theinferred mean Li value and dispersion in several {T}_eff and metallicityintervals. The resulting mean Li values along the plateau for [Fe/H]≤ 1.5 are A(Li)_NLTE = 2.214±0.093 and 2.224±0.075when the lowest effective temperature considered is taken equal to 5700K and 6000 K respectively. This is a factor of 2.48 to 2.81 (dependingon the adopted SBBN model and on the effective temperature range chosento delimit the plateau) lower than the CMB+SBBN determination. We findno evidence of intrinsic dispersion. Assuming the correctness of theCMB+SBBN prediction, we are then left with the conclusion that the Liabundance along the plateau is not the pristine one, but that halo starshave undergone surface depletion during their evolution. In the secondpart of the paper we further dissect our sample in search of newconstraints on Li depletion in halo stars. By means of the Hipparcosparallaxes, we derive the evolutionary status of each of our samplestars, and re-discuss our derived Li abundances. A very surprisingresult emerges for the first time from this examination. Namely, themean Li value as well as the dispersion appear to be lower (althoughfully compatible within the errors) for the dwarfs than for the turnoffand subgiant stars. For our most homogeneous dwarfs-only sample with[Fe/H] ≤ 1.5, the mean Li abundances are A(L)_NLTE = 2.177±0.071 and 2.215±0.074 when the lowest effective temperatureconsidered is taken equal to 5700 K and 6000 K respectively. This is afactor of 2.52 to 3.06 (depending on the selected range in {T}_eff forthe plateau and on the SBBN predictions we compare to) lower than theCMB+SBBN primordial value. Instead, for the post-main sequence stars thecorresponding values are 2.260±0.1 and 2.235±0.077, whichcorrespond to a depletion factor of 2.28 to 2.52. These results,together with the finding that all the stars with Li abnormalities(strong deficiency or high content) lie on or originate from the hotside of the plateau, lead us to suggest that the most massive of thehalo stars have had a slightly different Li history than their lessmassive contemporaries. In turn, this puts strong new constraints on thepossible depletion mechanisms and reinforces Li as a stellartomographer.

The Rise of the s-Process in the Galaxy
From newly obtained high-resolution, high signal-to-noise ratio spectrathe abundances of the elements La and Eu have been determined over thestellar metallicity range -3<[Fe/H]<+0.3 in 159 giant and dwarfstars. Lanthanum is predominantly made by the s-process in the solarsystem, while Eu owes most of its solar system abundance to ther-process. The changing ratio of these elements in stars over a widemetallicity range traces the changing contributions of these twoprocesses to the Galactic abundance mix. Large s-process abundances canbe the result of mass transfer from very evolved stars, so to identifythese cases we also report carbon abundances in our metal-poor stars.Results indicate that the s-process may be active as early as[Fe/H]=-2.6, although we also find that some stars as metal-rich as[Fe/H]=-1 show no strong indication of s-process enrichment. There is asignificant spread in the level of s-process enrichment even at solarmetallicity.

Stellar Chemical Signatures and Hierarchical Galaxy Formation
To compare the chemistries of stars in the Milky Way dwarf spheroidal(dSph) satellite galaxies with stars in the Galaxy, we have compiled alarge sample of Galactic stellar abundances from the literature. Whenkinematic information is available, we have assigned the stars tostandard Galactic components through Bayesian classification based onGaussian velocity ellipsoids. As found in previous studies, the[α/Fe] ratios of most stars in the dSph galaxies are generallylower than similar metallicity Galactic stars in this extended sample.Our kinematically selected stars confirm this for the Galactic halo,thin-disk, and thick-disk components. There is marginal overlap in thelow [α/Fe] ratios between dSph stars and Galactic halo stars onextreme retrograde orbits (V<-420 km s-1), but this is notsupported by other element ratios. Other element ratios compared in thispaper include r- and s-process abundances, where we find a significantoffset in the [Y/Fe] ratios, which results in a large overabundance in[Ba/Y] in most dSph stars compared with Galactic stars. Thus, thechemical signatures of most of the dSph stars are distinct from thestars in each of the kinematic components of the Galaxy. This resultrules out continuous merging of low-mass galaxies similar to these dSphsatellites during the formation of the Galaxy. However, we do not ruleout very early merging of low-mass dwarf galaxies, since up to one-halfof the most metal-poor stars ([Fe/H]<=-1.8) have chemistries that arein fair agreement with Galactic halo stars. We also do not rule outmerging with higher mass galaxies, although we note that the LMC and theremnants of the Sgr dwarf galaxy are also chemically distinct from themajority of the Galactic halo stars. Formation of the Galaxy's thickdisk by heating of an old thin disk during a merger is also not ruledout; however, the Galaxy's thick disk itself cannot be comprised of theremnants from a low-mass (dSph) dwarf galaxy, nor of a high-mass dwarfgalaxy like the LMC or Sgr, because of differences in chemistry.The new and independent environments offered by the dSph galaxies alsoallow us to examine fundamental assumptions related to thenucleosynthesis of the elements. The metal-poor stars ([Fe/H]<=-1.8)in the dSph galaxies appear to have lower [Ca/Fe] and [Ti/Fe] than[Mg/Fe] ratios, unlike similar metallicity stars in the Galaxy.Predictions from the α-process (α-rich freeze-out) would beconsistent with this result if there have been a lack of hypernovae indSph galaxies. The α-process could also be responsible for thevery low Y abundances in the metal-poor stars in dSph's; since [La/Eu](and possibly [Ba/Eu]) are consistent with pure r-process results, thelow [Y/Eu] suggests a separate r-process site for this light(first-peak) r-process element. We also discuss SNe II rates and yieldsas other alternatives, however. In stars with higher metallicities([Fe/H]>=-1.8), contributions from the s-process are expected; [(Y,La, and Ba)/Eu] all rise as expected, and yet [Ba/Y] is still muchhigher in the dSph stars than similar metallicity Galactic stars. Thisresult is consistent with s-process contributions from lower metallicityAGB stars in dSph galaxies, and is in good agreement with the slowerchemical evolution expected in the low-mass dSph galaxies relative tothe Galaxy, such that the build-up of metals occurs over much longertimescales. Future investigations of nucleosynthetic constraints (aswell as galaxy formation and evolution) will require an examination ofmany stars within individual dwarf galaxies.Finally, the Na-Ni trend reported in 1997 by Nissen & Schuster isconfirmed in Galactic halo stars, but we discuss this in terms of thegeneral nucleosynthesis of neutron-rich elements. We do not confirm thatthe Na-Ni trend is related to the accretion of dSph galaxies in theGalactic halo.

The Indo-US Library of Coudé Feed Stellar Spectra
We have obtained spectra for 1273 stars using the 0.9 m coudéfeed telescope at Kitt Peak National Observatory. This telescope feedsthe coudé spectrograph of the 2.1 m telescope. The spectra havebeen obtained with the no. 5 camera of the coudé spectrograph anda Loral 3K×1K CCD. Two gratings have been used to provide spectralcoverage from 3460 to 9464 Å, at a resolution of ~1 Å FWHMand at an original dispersion of 0.44 Å pixel-1. For885 stars we have complete spectra over the entire 3460 to 9464 Åwavelength region (neglecting small gaps of less than 50 Å), andpartial spectral coverage for the remaining stars. The 1273 stars havebeen selected to provide broad coverage of the atmospheric parametersTeff, logg, and [Fe/H], as well as spectral type. The goal ofthe project is to provide a comprehensive library of stellar spectra foruse in the automated classification of stellar and galaxy spectra and ingalaxy population synthesis. In this paper we discuss thecharacteristics of the spectral library, viz., details of theobservations, data reduction procedures, and selection of stars. We alsopresent a few illustrations of the quality and information available inthe spectra. The first version of the complete spectral library is nowpublicly available from the National Optical Astronomy Observatory(NOAO) via ftp and http.

Comparing Deep Mixing in Globular Cluster and Halo Field Giants: Carbon Abundance Data from the Literature
The behavior of carbon abundance as a function of luminosity is used tocompare the rates of deep mixing within red giants of four globularclusters and the Galactic halo field population. Measurements of [C/Fe]for the clusters M92, NGC 6397, M3, and M13 have been compiled from theliterature, together with the Gratton et al. data for halo field stars.Plots of [C/Fe] versus absolute visual magnitude show that forMV<+1.6 the rate of decline of carbon abundance withincreasing luminosity on the red giant branch isd[C/Fe]/dMV~0.22+/-0.03 among the field stars, as well as inM92, NGC 6397, and M3. Among giants fainter than MV=+1.6 thevariation of [C/Fe] with absolute magnitude is much less. The dataindicate that the rate at which deep mixing introduces carbon-depletedmaterial into the convective envelopes of field halo stars during theupper red giant branch phase of evolution is similar to that of manyglobular cluster giants. The notable exception appears to be M13, inwhich stars exhibit deep mixing at a greater rate; this may account forthe high incidence of very low oxygen abundances among the most luminousgiants in M13 in comparison to M3.

Oxygen Abundances in Metal-poor Stars
We present oxygen abundances derived from both the permitted andforbidden oxygen lines for 55 subgiants and giants with [Fe/H] valuesbetween -2.7 and solar with the goal of understanding the discrepancy inthe derived abundances. A first attempt, using Teff valuesfrom photometric calibrations and surface gravities from luminositiesobtained agreement between the indicators for turn-off stars, but thedisagreement was large for evolved stars. We find that the difference inthe oxygen abundances derived from the permitted and forbidden lines ismost strongly affected by Teff, and we derive a newTeff scale based on forcing the two sets of lines to give thesame oxygen abundances. These new parameters, however, do not agree withother observables, such as theoretical isochrones or Balmer-line profilebased Teff determinations. Our analysis finds thatone-dimensional, LTE analyses (with published non-LTE corrections forthe permitted lines) cannot fully resolve the disagreement in the twoindicators without adopting a temperature scale that is incompatiblewith other temperature indicators. We also find no evidence ofcircumstellar emission in the forbidden lines, removing such emission asa possible cause for the discrepancy.

Abundances of Cu and Zn in metal-poor stars: Clues for Galaxy evolution
We present new observations of copper and zinc abundances in 90metal-poor stars, belonging to the metallicity range -3<[Fe/H]<-0.5. The present study is based on high resolutionspectroscopic measurements collected at the Haute Provence Observatoire(R= 42 000, S/N>100). The trend of Cu and Zn abundances as a functionof the metallicity [Fe/H] is discussed and compared to that of otherheavy elements beyond iron. We also estimate spatial velocities andgalactic orbital parameters for our target stars in order to disentanglethe population of disk stars from that of halo stars using kinematiccriteria. In the absence of a firm a priori knowledge of thenucleosynthesis mechanisms controlling Cu and Zn production, and of therelative stellar sites, we derive constraints on these last from thetrend of the observed ratios [Cu/Fe] and [Zn/Fe] throughout the historyof the Galaxy, as well as from a few well established properties ofbasic nucleosynthesis processes in stars. We thus confirm that theproduction of Cu and Zn requires a number of different sources (neutroncaptures in massive stars, s-processing in low and intermediate massstars, explosive nucleosynthesis in various supernova types). We alsoattempt a ranking of the relative roles played by different productionmechanisms, and verify these hints through a simple estimate of thegalactic enrichment in Cu and Zn. In agreement with suggestionspresented earlier, we find evidence that type Ia Supernovae must play arelevant role, especially for the production of Cu. Based on the spectracollected with the 1.93-m telescope of Haute Provence Observatory.

The r-Process in the Early Galaxy
We report Sr, Pd, and Ag abundances for a sample of metal-poor fieldgiants and analyze a larger sample of Y, Zr, and Ba abundances. The[Y/Zr] and [Pd/Ag] abundance ratios are similar to those measured forthe r-process-rich stars CS 22892-052 and CS 31082-001. The [Pd/Ag]ratio is larger than predicted from the solar system r-processabundances. The constant [Y/Zr] and [Sr/Y] values in the field starsplace strong limits on the contributions of the weak s-process and themain s-process to the light neutron-capture elements. Stars in theglobular cluster M15 possess lower [Y/Zr] values than the field stars.There is a large dispersion in [Y/Ba]. Because the r-process isresponsible for the production of the heavy elements in the earlyGalaxy, these dispersions require varying light-to-heavy ratios inr-process yields.

Abundances of 30 Elements in 23 Metal-Poor Stars
We report the abundances of 30 elements in 23 metal-poor([Fe/H]<-1.7) giants. These are based on 7774 equivalent widths andspectral synthesis of 229 additional lines. Hyperfine splitting is takeninto account when appropriate. Our choice of model atmospheres has themost influence on the accuracy of our abundances. We consider the effectof different model atmospheres on our results. In addition to the randomerrors in Teff, logg, and microturbulent velocity, there areseveral sources of systematic error. These include using Teffdetermined from Fe I lines rather than colors, ignoring non-LTE effectson the Fe I/Fe II ionization balance, using models with solar[α/Fe] ratios, and using Kurucz models with overshooting. Ofthese, only the use of models with solar [α/Fe] ratios had anegligible effect. However, while the absolute abundances can change bygreater than 0.10 dex, the relative abundances, especially betweenclosely allied atoms such as the rare earth group, often show only small(less than 0.03 dex) changes. We found that some strong lines of Fe I,Mn I, and Cr I consistently gave lower abundances by ~0.2 dex, a numberlarger than the quoted errors in the gf-values. After considering amodel with depth-dependent microturbulent velocity and a model withhotter temperatures in the upper layers, we conclude that the latter dida better job of resolving the problem and agreeing with observationalevidence for the structure of stars. The error analysis includes theeffects of correlation of Teff, logg, and ξ errors, whichis crucial for certain element ratios, such as [Mg/Fe]. The abundancespresented here are being analyzed and discussed in a separate series ofpapers.

Three-dimensional Spectral Classification of Low-Metallicity Stars Using Artificial Neural Networks
We explore the application of artificial neural networks (ANNs) for theestimation of atmospheric parameters (Teff, logg, and [Fe/H])for Galactic F- and G-type stars. The ANNs are fed withmedium-resolution (Δλ~1-2 Å) non-flux-calibratedspectroscopic observations. From a sample of 279 stars with previoushigh-resolution determinations of metallicity and a set of (external)estimates of temperature and surface gravity, our ANNs are able topredict Teff with an accuracy ofσ(Teff)=135-150 K over the range4250<=Teff<=6500 K, logg with an accuracy ofσ(logg)=0.25-0.30 dex over the range 1.0<=logg<=5.0 dex, and[Fe/H] with an accuracy σ([Fe/H])=0.15-0.20 dex over the range-4.0<=[Fe/H]<=0.3. Such accuracies are competitive with theresults obtained by fine analysis of high-resolution spectra. It isnoteworthy that the ANNs are able to obtain these results withoutconsideration of photometric information for these stars. We have alsoexplored the impact of the signal-to-noise ratio (S/N) on the behaviorof ANNs and conclude that, when analyzed with ANNs trained on spectra ofcommensurate S/N, it is possible to extract physical parameter estimatesof similar accuracy with stellar spectra having S/N as low as 13. Takentogether, these results indicate that the ANN approach should be ofprimary importance for use in present and future large-scalespectroscopic surveys.

Th Ages for Metal-poor Stars
With a sample of 22 metal-poor stars, we demonstrate that theheavy-element abundance pattern (Z>=56) is the same as the r-processcontributions to the solar nebula. This bolsters the results of previousstudies that there is a universal r-process production pattern. We usethe abundance of thorium in five metal-poor stars, along with anestimate of the initial Th abundance based on the abundances of stabler-process elements, to measure their ages. We have four field red giantswith errors of 4.2 Gyr in their ages and one M92 giant with an error of5.6 Gyr, based on considering the sources of observational error only.We obtain an average age of 11.4 Gyr, which depends critically on theassumption of an initial Th/Eu production ratio of 0.496. If theuniverse is 15 Gyr old, then the (Th/Eu)0 should be 0.590, inagreement with some theoretical models of the r-process.

Analysis of neutron capture elements in metal-poor stars
We derived model atmosphere parameters (Teff, log g, [Fe/H],Vt) for 90 metal-deficient stars (-0.5<[Fe/H]<-3),using echelle spectra from the ELODIE library (Soubiran et al.\cite{soubet98}). These parameters were analyzed and compared withcurrent determinations by other authors. The study of the followingelements was carried out: Mg, Si, Ca, Sr, Y, Ba, La, Ce, Nd, and Eu. Therelative contributions of s- and r-processes were evaluated andinterpreted through theoretical computations of the chemical evolutionof the Galaxy. The chemical evolution models (Pagel &Tautvaišienė \cite{pagta95}; Timmes et al. \cite{timet95})depict quite well the behaviour of [Si/Fe], [Ca/Fe] with [Fe/H]. Thetrend of [Mg/Fe] compares more favourably with the computations of Pagel& Tautvaišienė (\cite{pagta95}) than those of Timmes etal. (\cite{timet95}). The runs of n-capture elements vs. metallicity aredescribed well both by the model of Pagel & Tautvaišienė(\cite{pagta95}, \cite{pagta97}) and by the model of Travaglio et al.(\cite{travet99}) at [Fe/H]>-1.5, when the matter of the Galaxy issufficiently homogeneous. The analysis of n-capture element abundancesconfirms the jump in [Ba/Fe] at [Fe/H]=-2.5. Some stars from our sampleat [Fe/H]<-2.0 show a large scatter of Sr, Ba, Y, Ce. This scatter isnot caused by the errors in the measurements, and may reflect theinhomogeneous nature of the prestellar medium at early stages ofgalactic evolution. The matching of [Ba/Fe], [Eu/Fe] vs. [Fe/H] with theinhomogeneous model by Travaglio et al. (\cite{travet01a}) suggests thatat [Fe/H]<-2.5, the essential contribution to the n-rich elementabundances derives from the r-process. The main sources of theseprocesses may be low mass SN II. The larger dispersion of s-processelement abundances with respect to alpha -rich elements may arise bothfrom the birth of metal-poor stars in globular clusters with followingdifferent evolutionary paths and (or) from differences in s-elementenrichment in Galaxy populations. Based on spectra collected at theObservatoire de Haute-Provence (OHP), France

On the stellar content of the open clusters Melotte 105, Hogg 15, Pismis 21 and Ruprecht 140
CCD observations in the B, V and I passbands have been used to generatecolour-magnitude diagrams reaching down to V ~ 19 mag for two slightlycharacterized (Melotte 105 and Hogg 15) and two almost unstudied (Pismis21 and Ruprecht 140) open clusters. The sample consists of about 1300stars observed in fields of about 4arcmin x4arcmin . Our analysis showsthat neither Pismis 21 nor Ruprecht 140 are genuine open clusters sinceno clear main sequences or other meaningful features can be seen intheir colour-magnitude diagrams. Melotte 105 and Hogg 15 are openclusters affected by E(B-V) = 0.42 +/- 0.03 and 0.95 +/- 0.05,respectively. Their distances to the Sun have been estimated as 2.2 +/-0.3 and 2.6 +/- 0.08 kpc, respectively, while the corresponding agesestimated from empirical isochrones fitted to the Main Sequence clustermembers are ~ 350 Myr and 300 Myr, respectively. The present data arenot consistent with the membership of the WN6 star HDE 311884 to Hogg15. Tables 2 to 5 are only available in electronic form at the CDS viaanonymous ftp to cdsarc.u-strasbg.fr (130.793.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/370/931

A database of high and medium-resolution stellar spectra
We present a database of 908 spectra of 709 stars obtained with theELODIE spectrograph at the Observatoire de Haute-Provence. 52 orders ofthe echelle spectra have been carefully fitted together to providecontinuous, high-resolution spectra in the wavelength range lambdalambda = 410-680 nm. The archive provides a large coverage of the spaceof atmospheric parameters: T_eff from 3700 K to 13 600 K, log g from0.03 to 5.86 and [Fe/H] from -2.8 to +0.7. At the nominal resolution,R=42 000, the mean signal-to-noise ratio is 150 per pixel. The spectragiven at this resolution are normalized to their pseudo-continuum andare intended to serve for abundance studies, spectral classification andtests of stellar atmosphere models. A lower resolution version of thearchive, at R=10 000, is calibrated in physical flux with a broad-bandphotometric precision of 2.5% and narrow-band precision of 0.5%. It iswell suited to stellar population synthesis of galaxies and clusters,and to kinematical investigations of stellar systems. The archive isdistributed in FITS format through the HYPERCAT and CDS databases. Basedon observations made on the 193 cm telescope at the Haute-ProvenceObservatory, France. Table 1 is only available in electronic form at theCDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/369/1048

Detection of Metal-poor Stars in the Direction of the North Galactic Pole
A simple approach to detecting metal-poor stars is to measure amagnesium index, which depends on the Mg H band plus the three nearby Mgb lines and is derived through intermediate-band interference filters.An empirically established line of demarcation in the Mg index versusB-V diagram separates metal-poor stars from solar-abundance stars. Afurther separation between metal-poor dwarfs and giants depends on B-Vprimarily dwarfs for B-V<0.55, giants for B-V>0.7, with both dwarfsand giants falling in the transition region. For the metal-poor giantsthe distance from the demarcation line correlates well with [Fe/H],permitting estimates of stellar abundances. Stars in two regions on thesky in the vicinity of the north Galactic pole have been observed withsuch a set of filters. Eighteen stars (6% of the population of 299) inthe sample covering the V range 8.7 to 15.6 and 48 stars (31% of thepopulation of 163) in a deeper probe to V=19.9 found through thisprocess are suspected metal-poor stars according to their Mg indices.Twenty-three are specifically deemed giants, with<[Fe/H]><=-1.5.

Neutron-Capture Elements in the Early Galaxy: Insights from a Large Sample of Metal-poor Giants
New abundances for neutron-capture (n-capture) elements in a largesample of metal-poor giants from the Bond survey are presented. Thespectra were acquired with the KPNO 4 m echelle and coudé feedspectrographs, and have been analyzed using LTE fine-analysis techniqueswith both line analysis and spectral synthesis. Abundances of eightn-capture elements (Sr, Y, Zr, Ba, La, Nd, Eu, and Dy) in 43 stars havebeen derived from blue (λλ4070-4710, R~20,000, S/Nratio~100-200) echelle spectra and red (λλ6100-6180,R~22,000, S/N ratio~100-200) coudé spectra, and the abundance ofBa only has been derived from the red spectra for an additional 27stars. Overall, the abundances show clear evidence for a largestar-to-star dispersion in the heavy element-to-iron ratios. Thiscondition must have arisen from individual nucleosynthetic events inrapidly evolving halo progenitors that injected newly manufacturedn-capture elements into an inhomogeneous early Galactic halointerstellar medium. The new data also confirm that at metallicities[Fe/H]<~-2.4, the abundance pattern of the heavy (Z>=56) n-captureelements in most giants is well-matched to a scaled solar systemr-process nucleosynthesis pattern. The onset of the main r-process canbe seen at [Fe/H]~-2.9 this onset is consistent with the suggestion thatlow mass Type II supernovae are responsible for the r-process.Contributions from the s-process can first be seen in some stars withmetallicities as low as [Fe/H]~-2.75 and are present in most stars withmetallicities [Fe/H]>-2.3. The appearance of s-process contributionsas metallicity increases presumably reflects the longer stellarevolutionary timescale of the (low-mass) s-process nucleosynthesissites. The lighter n-capture elements (Sr-Y-Zr) are enhanced relative tothe heavier r-process element abundances. Their production cannot beattributed solely to any combination of the solar system r- and mains-processes, but requires a mixture of material from the r-process andfrom an additional n-capture process that can operate at early Galactictime. This additional process could be the weak s-process in massive(~25 Msolar) stars, or perhaps a second r-process site, i.e.,different from the site that produces the heavier (Z>=56) n-captureelements.

Kinematics of Metal-poor Stars in the Galaxy. II. Proper Motions for a Large Nonkinematically Selected Sample
We present a revised catalog of 2106 Galactic stars, selected withoutkinematic bias and with available radial velocities, distance estimates,and metal abundances in the range -4.0<=[Fe/H]<=0.0. This updateof the 1995 Beers & Sommer-Larsen catalog includes newly derivedhomogeneous photometric distance estimates, revised radial velocitiesfor a number of stars with recently obtained high-resolution spectra,and refined metallicities for stars originally identified in the HKobjective-prism survey (which account for nearly half of the catalog)based on a recent recalibration. A subset of 1258 stars in this cataloghave available proper motions based on measurements obtained with theHipparcos astrometry satellite or taken from the updated AstrographicCatalogue (second epoch positions from either the Hubble Space TelescopeGuide Star Catalog or the Tycho Catalogue), the Yale/San Juan SouthernProper Motion Catalog 2.0, and the Lick Northern Proper Motion Catalog.Our present catalog includes 388 RR Lyrae variables (182 of which arenewly added), 38 variables of other types, and 1680 nonvariables, withdistances in the range 0.1 to 40 kpc.

Estimation of Stellar Metal Abundance. II. A Recalibration of the Ca II K Technique, and the Autocorrelation Function Method
We have recalibrated a method for the estimation of stellar metalabundance, parameterized as [Fe/H], based on medium-resolution (1-2Å) optical spectra (the majority of which cover the wavelengthrange 3700-4500 Å). The equivalent width of the Ca II K line (3933Å) as a function of [Fe/H] and broadband B-V color, as predictedfrom spectrum synthesis and model atmosphere calculations, is comparedwith observations of 551 stars with high-resolution abundances availablefrom the literature (a sevenfold increase in the number of calibrationstars that were previously available). A second method, based on theFourier autocorrelation function technique first described by Ratnatunga& Freeman, is used to provide an independent estimate of [Fe/H], ascalibrated by comparison with 405 standard-star abundances.Metallicities based on a combination of the two techniques for dwarfsand giants in the color range 0.30<=(B-V)_0<=1.2 exhibit anexternal 1 sigma scatter of approximately 0.10-0.20 dex over theabundance range -4.0<=[Fe/H]<=0.5. Particular attention has beengiven to the determination of abundance estimates at the metal-rich endof the calibration, where our previous attempt suffered from aconsiderable zero-point offset. Radial velocities, accurate toapproximately 10 km s^-1, are reported for all 551 calibration stars.

Ca II H and K Photometry on the UVBY System. III. The Metallicity Calibration for the Red Giants
New photometry on the uvby Ca system is presented for over 300 stars.When combined with previous data, the sample is used to calibrate themetallicity dependence of the hk index for cooler, evolved stars. Themetallicity scale is based upon the standardized merger of spectroscopicabundances from 38 studies since 1983, providing an overlap of 122evolved stars with the photometric catalog. The hk index producesreliable abundances for stars in the [Fe/H] range from -0.8 to -3.4,losing sensitivity among cooler stars due to saturation effects athigher [Fe/H], as expected.

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TYCHO-2 2000TYC 6395-710-1
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