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Heavy Element Abundances in Giant Stars of the Globular Clusters M4 and M5
We present a comprehensive abundance analysis of 27 heavy elements inbright giant stars of the globular clusters M4 and M5 based onhigh-resolution, high signal-to-noise ratio spectra obtained with theMagellan Clay Telescope. We confirm and expand on previous results forthese clusters by showing that (1) all elements heavier than, andincluding, Si have constant abundances within each cluster, (2) theelements from Ca to Ni have indistinguishable compositions in M4 and M5,(3) Si, Cu, Zn, and all s-process elements are approximately 0.3 dexoverabundant in M4 relative to M5, and (4) the r-process elements Sm,Eu, Gd, and Th are slightly overabundant in M5 relative to M4. Thecluster-to-cluster abundance differences for Cu and Zn are intriguing,especially in light of their uncertain nucleosynthetic origins. Weconfirm that stars other than Type Ia supernovae must producesignificant amounts of Cu and Zn at or below the clusters'metallicities. If intermediate-mass AGB stars or massive stars areresponsible for the Cu and Zn enhancements in M4, the similar [Rb/Zr]ratios and (preliminary) Mg isotope ratios in both clusters may beproblematic for either scenario. For the elements from Ba to Hf, weassume that the s- and r-process contributions are scaled versions ofthe solar s- and r-process abundances. We quantify the relativefractions of s- and r-process material for each cluster and show thatthey provide an excellent fit to the observed abundances.Based on observations made with the Magellan Clay Telescope at LasCampanas Observatory.

Automated classification of ELODIE stellar spectral library using probabilistic artificial neural networks
A Probabilistic Neural Network model has been used for automatedclassification of ELODIE stellar spectral library consisting of about2000 spectra into 158 known spectro-luminosity classes. The full spectrawith 561 flux bins and a PCA reduced set of 57, 26 and 16 componentshave been used for the training and test sessions. The results show aspectral type classification accuracy of 3.2 sub-spectral type andluminosity class accuracy of 2.7 for the full spectra and an accuracy of3.1 and 2.6 respectively with the PCA set. This technique will be usefulfor future upcoming large databases and their rapid classification.

Rotation and Macroturbulence in Metal-Poor Field Red Giant and Red Horizontal Branch Stars
We report the results for rotational velocities, Vrot sin i,and macroturbulence dispersions, ζRT, for 12 metal-poorfield red giant branch (RGB) stars and 7 metal-poor field red horizontalbranch (RHB) stars. The results are based on Fourier transform analysesof absorption line profiles from high-resolution (R ≈ 120,000),high-S/N (≈215 per pixel; ≈345 per resolution element) spectraobtained with the Gecko spectrograph at the Canada-France-HawaiiTelescope (CFHT). The stars were selected from the authors' previousstudies of 20 RHB and 116 RGB stars, based primarily onlarger-than-average line-broadening values. We find thatζRT values for the metal-poor RGB stars are very similarto those for metal-rich disk giants studied earlier by Gray and hiscollaborators. Six of the RGB stars have small rotational values, lessthan 2.0 km s-1, while five show significantrotation/enhanced line broadening, over 3 km s-1. We confirmthe rapid rotation rate for RHB star HD 195636, found earlier byPreston. This star's rotation is comparable to that of the fastest knownrotating blue horizontal branch (BHB) stars, when allowance is made fordifferences in radii and moments of inertia. The other six RHB starshave somewhat lower rotation but show a trend to higher values at highertemperatures (lower radii). Comparing our results with those for BHBstars from Kinman et al., we find that the fraction of rapidly rotatingRHB stars is somewhat lower than is found among BHB stars. The number ofrapidly rotating RHB stars is also smaller than we would have expectedfrom the observed rotation of the RGB stars. We devise two empiricalmethods to translate our earlier line-broadening results intoVrot sin i for all the RGB and RHB stars they studied.Binning the RGB stars by luminosity, we find that most metal-poor fieldRGB stars show no detectable sign, on average, of rotation, which is notsurprising given the stars' large radii. However, the most luminousstars, with MV <= -1.5, do show net rotation, with meanvalues of 2-4 km s-1, depending on the algorithm employed,and also show signs of radial velocity jitter and mass loss. This"rotation" may in fact prove to be due to other line-broadening effects,such as shock waves or pulsation.Based on observations obtained at the Canada-France-Hawaii Telescope(CFHT) which is operated by the National Research Council of Canada, theInstitut National des Sciences de l'Univers of the Centre National de laRecherche Scientifique de France, and the University of Hawaii.

Vertical distribution of Galactic disk stars. IV. AMR and AVR from clump giants
We present the parameters of 891 stars, mostly clump giants, includingatmospheric parameters, distances, absolute magnitudes, spatialvelocities, galactic orbits and ages. One part of this sample consistsof local giants, within 100 pc, with atmospheric parameters eitherestimated from our spectroscopic observations at high resolution andhigh signal-to-noise ratio, or retrieved from the literature. The otherpart of the sample includes 523 distant stars, spanning distances up to1 kpc in the direction of the North Galactic Pole, for which we haveestimated atmospheric parameters from high resolution but lowsignal-to-noise Echelle spectra. This new sample is kinematicallyunbiased, with well-defined boundaries in magnitude and colours. Werevisit the basic properties of the Galactic thin disk as traced byclump giants. We find the metallicity distribution to be different fromthat of dwarfs, with fewer metal-rich stars. We find evidence for avertical metallicity gradient of -0.31 dex kpc-1 and for atransition at ~4-5 Gyr in both the metallicity and velocities. Theage-metallicity relation (AMR), which exhibits a very low dispersion,increases smoothly from 10 to 4 Gyr, with a steeper increase for youngerstars. The age-velocity relation (AVR) is characterized by thesaturation of the V and W dispersions at 5 Gyr, and continuous heatingin U.

Line Broadening in Field Metal-Poor Red Giant and Red Horizontal Branch Stars
We report 349 radial velocities for 45 metal-poor field red giant branch(RGB) and red horizontal branch (RHB) stars, with time coverage rangingfrom 1 to 21 years. We have identified one new spectroscopic binary, HD4306, and one possible such system, HD 184711. We also provide 57 radialvelocities for 11 of the 91 stars reported in our previous work. All butone of the 11 stars had been found to have variable radial velocities.New velocities for the long-period spectroscopic binaries BD-1 2582 andHD 108317 have extended the time coverage to 21.7 and 12.5 years,respectively, but in neither case have we yet completed a full orbitalperiod. As was found in the previous study, radial velocity "jitter" ispresent in many of the most luminous stars. Excluding stars showingspectroscopic binary orbital motion, all 7 of the red giants withestimated MV values more luminous than -2.0 display jitter,as well as 3 of the 14 stars with -2.0 < MV <= -1.4. Wehave also measured the line broadening in all the new spectra, usingsynthetic spectra as templates. Comparison with results fromhigh-resolution and higher signal-to-noise (S/N) spectra employed byother workers shows good agreement down to line-broadening levels of 3km s-1, well below our instrumental resolution of 8.5 kms-1. As the previous work demonstrated, the majority of themost luminous red giants show significant line broadening, as do many ofthe red horizontal branch stars, and we briefly discuss possible causes.The line broadening appears related to velocity jitter, in that bothappear primarily among the highest luminosity red giants.

Halo Star Streams in the Solar Neighborhood
We have assembled a sample of halo stars in the solar neighborhood tolook for halo substructure in velocity and angular momentum space. Oursample (231 stars) includes red giants, RR Lyrae variable stars, and redhorizontal branch stars within 2.5 kpc of the Sun with [Fe/H] less than-1.0. It was chosen to include stars with accurate distances, spacevelocities, and metallicities, as well as well-quantified errors. Withour data set, we confirm the existence of the streams found by Helmi andcoworkers, which we refer to as the H99 streams. These streams have adouble-peaked velocity distribution in the z-direction (out of theGalactic plane). We use the results of modeling of the H99 streams byHelmi and collaborators to test how one might use vz velocityinformation and radial velocity information to detect kinematicsubstructure in the halo. We find that detecting the H99 streams withradial velocities alone would require a large sample (e.g.,approximately 150 stars within 2 kpc of the Sun and within 20° ofthe Galactic poles). In addition, we use the velocity distribution ofthe H99 streams to estimate their age. From our model of the progenitorof the H99 streams, we determine that it was accreted between 6 and 9Gyr ago. The H99 streams have [α/Fe] abundances similar to otherhalo stars in the solar neighborhood, suggesting that the gas thatformed these stars were enriched mostly by Type II supernovae. We havealso discovered in angular momentum space two other possiblesubstructures, which we refer to as the retrograde and progradeoutliers. The retrograde outliers are likely to be halo substructure,but the prograde outliers are most likely part of the smooth halo. Theretrograde outliers have significant structure in the vφdirection and show a range of [α/Fe], with two having low[α/Fe] for their [Fe/H]. The fraction of substructure stars in oursample is between 5% and 7%. The methods presented in this paper can beused to exploit the kinematic information present in future largedatabases like RAVE, SDSS-II/SEGUE, and Gaia.

Medium-resolution Isaac Newton Telescope library of empirical spectra - II. The stellar atmospheric parameters
We present a homogeneous set of stellar atmospheric parameters(Teff, logg, [Fe/H]) for MILES, a new spectral stellarlibrary covering the range λλ 3525-7500Å at2.3Å (FWHM) spectral resolution. The library consists of 985 starsspanning a large range in atmospheric parameters, from super-metal-rich,cool stars to hot, metal-poor stars. The spectral resolution, spectraltype coverage and number of stars represent a substantial improvementover previous libraries used in population synthesis models. Theatmospheric parameters that we present here are the result of aprevious, extensive compilation from the literature. In order toconstruct a homogeneous data set of atmospheric parameters we have takenthe sample of stars of Soubiran, Katz & Cayrel, which has very welldetermined fundamental parameters, as the standard reference system forour field stars, and have calibrated and bootstrapped the data fromother papers against it. The atmospheric parameters for our clusterstars have also been revised and updated according to recent metallicityscales, colour-temperature relations and improved set of isochrones.

Pulkovo compilation of radial velocities for 35495 stars in a common system.
Not Available

Medium-resolution Isaac Newton Telescope library of empirical spectra
A new stellar library developed for stellar population synthesismodelling is presented. The library consists of 985 stars spanning alarge range in atmospheric parameters. The spectra were obtained at the2.5-m Isaac Newton Telescope and cover the range λλ3525-7500 Å at 2.3 Å (full width at half-maximum) spectralresolution. The spectral resolution, spectral-type coverage,flux-calibration accuracy and number of stars represent a substantialimprovement over previous libraries used in population-synthesis models.

The Hamburg/ESO R-process enhanced star survey (HERES). III. HE 0338-3945 and the formation of the r + s stars
We have derived abundances of 33 elements and upper limits for 6additional elements for the metal-poor ([Fe/H] = -2.42) turn-off star HE0338-3945 from high-quality VLT-UVES spectra. The star is heavilyenriched, by about a factor of 100 relative to iron and the Sun, in theheavy s-elements (Ba, La, ...). It is also heavily enriched in Eu, whichis generally considered an r-element, and in other similar elements. Itis less enriched, by about a factor of 10, in the lighter s-elements(Sr, Y and Zr). C is also strongly enhanced and, to a somewhat lesserdegree, N and O. These abundance estimates are subject to severeuncertainties due to NLTE and thermal inhomogeneities which are nottaken into detailed consideration. However, an interesting result, whichis most probably robust in spite of these uncertainties, emerges: theabundances derived for this star are very similar to those of otherstars with an overall enhancement of all elements beyond the iron peak.We have defined criteria for this class of stars, r+s stars, and discussnine different scenarios to explain their origin. None of theseexplanations is found to be entirely convincing. The most plausiblehypotheses involve a binary system in which the primary component goesthrough its giant branch and asymptotic giant branch phases and producesCNO and s-elements which are dumped onto the observed star. Whether ther-element Eu is produced by supernovae before the star was formed(perhaps triggering the formation of a low-mass binary), by a companionas it explodes as a supernova (possibly triggered by mass transfer), orwhether it is possibly produced in a high-neutron-density version of thes-process is still unclear. Several suggestions are made on how toclarify this situation.

Estimation of Carbon Abundances in Metal-Poor Stars. I. Application to the Strong G-Band Stars of Beers, Preston, and Shectman
We develop and test a method for the estimation of metallicities([Fe/H]) and carbon abundance ratios ([C/Fe]) for carbon-enhancedmetal-poor (CEMP) stars based on the application of artificial neuralnetworks, regressions, and synthesis models to medium-resolution (1-2Å) spectra and J-K colors. We calibrate this method by comparisonwith metallicities and carbon abundance determinations for 118 starswith available high-resolution analyses reported in the recentliterature. The neural network and regression approaches make use of apreviously defined set of line-strength indices quantifying the strengthof the Ca II K line and the CH G band, in conjunction with J-K colorsfrom the Two Micron All Sky Survey Point Source Catalog. The use ofnear-IR colors, as opposed to broadband B-V colors, is required becauseof the potentially large affect of strong molecular carbon bands onbluer color indices. We also explore the practicality of obtainingestimates of carbon abundances for metal-poor stars from the spectralinformation alone, i.e., without the additional information provided byphotometry, as many future samples of CEMP stars may lack such data. Wefind that although photometric information is required for theestimation of [Fe/H], it provides little improvement in our derivedestimates of [C/Fe], and hence, estimates of carbon-to-iron ratios basedsolely on line indices appear sufficiently accurate for most purposes.Although we find that the spectral synthesis approach yields the mostaccurate estimates of [C/Fe], in particular for the stars with thestrongest molecular bands, it is only marginally better than is obtainedfrom the line index approaches. Using these methods we are able toreproduce the previously measured [Fe/H] and [C/Fe] determinations withan accuracy of ~0.25 dex for stars in the metallicity interval-5.5<=[Fe/H]<=-1.0 and with 0.2<=(J-K)0<=0.8. Athigher metallicity, the Ca II K line begins to saturate, especially forthe cool stars in our program, and hence, this approach is not useful insome cases. As a first application, we estimate the abundances of [Fe/H]and [C/Fe] for the 56 stars identified as possibly carbon-rich, relativeto stars of similar metal abundance, in the sample of ``strong G-band''stars discussed by Beers, Preston, and Shectman.

The Rise of the s-Process in the Galaxy
From newly obtained high-resolution, high signal-to-noise ratio spectrathe abundances of the elements La and Eu have been determined over thestellar metallicity range -3<[Fe/H]<+0.3 in 159 giant and dwarfstars. Lanthanum is predominantly made by the s-process in the solarsystem, while Eu owes most of its solar system abundance to ther-process. The changing ratio of these elements in stars over a widemetallicity range traces the changing contributions of these twoprocesses to the Galactic abundance mix. Large s-process abundances canbe the result of mass transfer from very evolved stars, so to identifythese cases we also report carbon abundances in our metal-poor stars.Results indicate that the s-process may be active as early as[Fe/H]=-2.6, although we also find that some stars as metal-rich as[Fe/H]=-1 show no strong indication of s-process enrichment. There is asignificant spread in the level of s-process enrichment even at solarmetallicity.

Stellar Chemical Signatures and Hierarchical Galaxy Formation
To compare the chemistries of stars in the Milky Way dwarf spheroidal(dSph) satellite galaxies with stars in the Galaxy, we have compiled alarge sample of Galactic stellar abundances from the literature. Whenkinematic information is available, we have assigned the stars tostandard Galactic components through Bayesian classification based onGaussian velocity ellipsoids. As found in previous studies, the[α/Fe] ratios of most stars in the dSph galaxies are generallylower than similar metallicity Galactic stars in this extended sample.Our kinematically selected stars confirm this for the Galactic halo,thin-disk, and thick-disk components. There is marginal overlap in thelow [α/Fe] ratios between dSph stars and Galactic halo stars onextreme retrograde orbits (V<-420 km s-1), but this is notsupported by other element ratios. Other element ratios compared in thispaper include r- and s-process abundances, where we find a significantoffset in the [Y/Fe] ratios, which results in a large overabundance in[Ba/Y] in most dSph stars compared with Galactic stars. Thus, thechemical signatures of most of the dSph stars are distinct from thestars in each of the kinematic components of the Galaxy. This resultrules out continuous merging of low-mass galaxies similar to these dSphsatellites during the formation of the Galaxy. However, we do not ruleout very early merging of low-mass dwarf galaxies, since up to one-halfof the most metal-poor stars ([Fe/H]<=-1.8) have chemistries that arein fair agreement with Galactic halo stars. We also do not rule outmerging with higher mass galaxies, although we note that the LMC and theremnants of the Sgr dwarf galaxy are also chemically distinct from themajority of the Galactic halo stars. Formation of the Galaxy's thickdisk by heating of an old thin disk during a merger is also not ruledout; however, the Galaxy's thick disk itself cannot be comprised of theremnants from a low-mass (dSph) dwarf galaxy, nor of a high-mass dwarfgalaxy like the LMC or Sgr, because of differences in chemistry.The new and independent environments offered by the dSph galaxies alsoallow us to examine fundamental assumptions related to thenucleosynthesis of the elements. The metal-poor stars ([Fe/H]<=-1.8)in the dSph galaxies appear to have lower [Ca/Fe] and [Ti/Fe] than[Mg/Fe] ratios, unlike similar metallicity stars in the Galaxy.Predictions from the α-process (α-rich freeze-out) would beconsistent with this result if there have been a lack of hypernovae indSph galaxies. The α-process could also be responsible for thevery low Y abundances in the metal-poor stars in dSph's; since [La/Eu](and possibly [Ba/Eu]) are consistent with pure r-process results, thelow [Y/Eu] suggests a separate r-process site for this light(first-peak) r-process element. We also discuss SNe II rates and yieldsas other alternatives, however. In stars with higher metallicities([Fe/H]>=-1.8), contributions from the s-process are expected; [(Y,La, and Ba)/Eu] all rise as expected, and yet [Ba/Y] is still muchhigher in the dSph stars than similar metallicity Galactic stars. Thisresult is consistent with s-process contributions from lower metallicityAGB stars in dSph galaxies, and is in good agreement with the slowerchemical evolution expected in the low-mass dSph galaxies relative tothe Galaxy, such that the build-up of metals occurs over much longertimescales. Future investigations of nucleosynthetic constraints (aswell as galaxy formation and evolution) will require an examination ofmany stars within individual dwarf galaxies.Finally, the Na-Ni trend reported in 1997 by Nissen & Schuster isconfirmed in Galactic halo stars, but we discuss this in terms of thegeneral nucleosynthesis of neutron-rich elements. We do not confirm thatthe Na-Ni trend is related to the accretion of dSph galaxies in theGalactic halo.

The Indo-US Library of Coudé Feed Stellar Spectra
We have obtained spectra for 1273 stars using the 0.9 m coudéfeed telescope at Kitt Peak National Observatory. This telescope feedsthe coudé spectrograph of the 2.1 m telescope. The spectra havebeen obtained with the no. 5 camera of the coudé spectrograph anda Loral 3K×1K CCD. Two gratings have been used to provide spectralcoverage from 3460 to 9464 Å, at a resolution of ~1 Å FWHMand at an original dispersion of 0.44 Å pixel-1. For885 stars we have complete spectra over the entire 3460 to 9464 Åwavelength region (neglecting small gaps of less than 50 Å), andpartial spectral coverage for the remaining stars. The 1273 stars havebeen selected to provide broad coverage of the atmospheric parametersTeff, logg, and [Fe/H], as well as spectral type. The goal ofthe project is to provide a comprehensive library of stellar spectra foruse in the automated classification of stellar and galaxy spectra and ingalaxy population synthesis. In this paper we discuss thecharacteristics of the spectral library, viz., details of theobservations, data reduction procedures, and selection of stars. We alsopresent a few illustrations of the quality and information available inthe spectra. The first version of the complete spectral library is nowpublicly available from the National Optical Astronomy Observatory(NOAO) via ftp and http.

Empirically Constrained Color-Temperature Relations. II. uvby
A new grid of theoretical color indices for the Strömgren uvbyphotometric system has been derived from MARCS model atmospheres and SSGsynthetic spectra for cool dwarf and giant stars having-3.0<=[Fe/H]<=+0.5 and 3000<=Teff<=8000 K. Atwarmer temperatures (i.e., 8000-2.0. To overcome thisproblem, the theoretical indices at intermediate and high metallicitieshave been corrected using a set of color calibrations based on fieldstars having well-determined distances from Hipparcos, accurateTeff estimates from the infrared flux method, andspectroscopic [Fe/H] values. In contrast with Paper I, star clustersplayed only a minor role in this analysis in that they provided asupplementary constraint on the color corrections for cool dwarf starswith Teff<=5500 K. They were mainly used to test thecolor-Teff relations and, encouragingly, isochrones thatemploy the transformations derived in this study are able to reproducethe observed CMDs (involving u-v, v-b, and b-y colors) for a number ofopen and globular clusters (including M67, the Hyades, and 47 Tuc)rather well. Moreover, our interpretations of such data are verysimilar, if not identical, with those given in Paper I from aconsideration of BV(RI)C observations for the sameclusters-which provides a compelling argument in support of thecolor-Teff relations that are reported in both studies. Inthe present investigation, we have also analyzed the observedStrömgren photometry for the classic Population II subdwarfs,compared our ``final'' (b-y)-Teff relationship with thosederived empirically in a number of recent studies and examined in somedetail the dependence of the m1 index on [Fe/H].Based, in part, on observations made with the Nordic Optical Telescope,operated jointly on the island of La Palma by Denmark, Finland, Iceland,Norway, and Sweden, in the Spanish Observatorio del Roque de losMuchachos of the Instituto de Astrofisica de Canarias.Based, in part, on observations obtained with the Danish 1.54 mtelescope at the European Southern Observatory, La Silla, Chile.

Rotation Velocities of Red and Blue Field Horizontal-Branch Stars
We present measurements of the projected stellar rotation velocities(vsini) of a sample of 45 candidate field horizontal-branch (HB) starsspanning a wide range of effective temperatures, from red HB stars withTeff~=5000K to blue HB stars with Teff of 17,000K.Among the cooler blue HB stars (Teff=7500-11500 K), weconfirm prior studies showing that, although a majority of stars rotateat vsini<15kms-1, there exists a subset of ``fastrotators'' with vsini as high as 30-35 km s-1. All but one ofthe red HB stars in our sample have vsini<10kms-1, and noanalogous rotation bimodality is evident. We also identify anarrow-lined hot star (Teff~=16,000K) with enhancedphotospheric metal abundances and helium depletion, similar to theabundance patterns found among hot BHB stars in globular clusters, andfour other stars that may also belong in this category. We discussdetails of the spectral line fitting procedure that we use to deducevsini and explore how measurements of field HB star rotation may shedlight on the issue of HB star rotation in globular clusters.

Comparing Deep Mixing in Globular Cluster and Halo Field Giants: Carbon Abundance Data from the Literature
The behavior of carbon abundance as a function of luminosity is used tocompare the rates of deep mixing within red giants of four globularclusters and the Galactic halo field population. Measurements of [C/Fe]for the clusters M92, NGC 6397, M3, and M13 have been compiled from theliterature, together with the Gratton et al. data for halo field stars.Plots of [C/Fe] versus absolute visual magnitude show that forMV<+1.6 the rate of decline of carbon abundance withincreasing luminosity on the red giant branch isd[C/Fe]/dMV~0.22+/-0.03 among the field stars, as well as inM92, NGC 6397, and M3. Among giants fainter than MV=+1.6 thevariation of [C/Fe] with absolute magnitude is much less. The dataindicate that the rate at which deep mixing introduces carbon-depletedmaterial into the convective envelopes of field halo stars during theupper red giant branch phase of evolution is similar to that of manyglobular cluster giants. The notable exception appears to be M13, inwhich stars exhibit deep mixing at a greater rate; this may account forthe high incidence of very low oxygen abundances among the most luminousgiants in M13 in comparison to M3.

Oxygen Abundances in Metal-poor Stars
We present oxygen abundances derived from both the permitted andforbidden oxygen lines for 55 subgiants and giants with [Fe/H] valuesbetween -2.7 and solar with the goal of understanding the discrepancy inthe derived abundances. A first attempt, using Teff valuesfrom photometric calibrations and surface gravities from luminositiesobtained agreement between the indicators for turn-off stars, but thedisagreement was large for evolved stars. We find that the difference inthe oxygen abundances derived from the permitted and forbidden lines ismost strongly affected by Teff, and we derive a newTeff scale based on forcing the two sets of lines to give thesame oxygen abundances. These new parameters, however, do not agree withother observables, such as theoretical isochrones or Balmer-line profilebased Teff determinations. Our analysis finds thatone-dimensional, LTE analyses (with published non-LTE corrections forthe permitted lines) cannot fully resolve the disagreement in the twoindicators without adopting a temperature scale that is incompatiblewith other temperature indicators. We also find no evidence ofcircumstellar emission in the forbidden lines, removing such emission asa possible cause for the discrepancy.

A grid of synthetic spectra and indices Fe5270, Fe5335, Mgb and Mg2 as a function of stellar parameters and [alpha/Fe]
We have computed a grid of synthetic spectra in the wavelength rangelambda lambda 4600-5600 Å using revised model atmospheres, for arange of atmospheric parameters and values of [alpha -elements/Fe] = 0.0and +0.4. The Lick indices Fe5270, Fe5335, Mgb and Mg2 aremeasured on the grid spectra for FWHM = 2 to 8.3 Å. Relationsbetween the indices Fe5270, Fe5335 and Mg2 and the stellarparameters effective temperature Teff, log ; g, [Fe/H] and[alpha /Fe], valid in the range 4000 <= Teff <= 7000 K,are presented. These fitting functions are given for FWHM = 3.5 and 8.3Å. The indices were also measured for a list of 97 reference starswith well-known stellar parameters observed at ESO and OHP, and theseare compared to the computed indices. Finally, a comparison of theindices measured on the observed spectra and those derived from thefitting functions based on synthetic spectra is presented.Observations collected at the European Southern Observatory (ESO), LaSilla, Chile and at the Observatoire de Haute Provence (OHP), St-Michel,France.All Tables of Appendices A and B are only available in electronic format the CDS via anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) orvia http://cdsweb.u-strasbg.fr/cgi-bin/qcat?/A+A/404/661

Sodium Abundances in Stellar Atmospheres with Differing Metallicities
The non-LTE sodium abundances of 100 stars with metallicities-3<[Fe/H]<0.3 are determined using high-dispersion spectra withhigh signal-to-noise ratios. The sodium abundances [Na/Fe] obtained areclose to the solar abundance and display a smaller scatter than valuespublished previously. Giants (logg<3.8) with [Fe/H]<-1 do notdisplay overabundances of sodium, and their sodium abundances do notshow an anticorrelation with the oxygen abundance, in contrast toglobular-cluster giants. They likewise do not show sodium-abundancevariations with motion along the giant branch. No appreciable decreasein the sodium abundance was detected for dwarfs (logg>3.8) withmetallicities -2<[Fe/H]<-1. The observed relation between [Na/Fe]and [Fe/H] is in satisfactory agreement with the theoreticalcomputations of Samland, which take into account the metallicitydependence of the sodium yield and a number of other factors affectingthe distribution of elements in the Galaxy during the course of itsevolution.

Oxygen line formation in late-F through early-K disk/halo stars. Infrared O I triplet and [O I] lines
In order to investigate the formation of O I 7771-5 and [O I] 6300/6363lines, extensive non-LTE calculations for neutral atomic oxygen werecarried out for wide ranges of model atmosphere parameters, which areapplicable to early-K through late-F halo/disk stars of variousevolutionary stages.The formation of the triplet O I lines was found to be well described bythe classical two-level-atom scattering model, and the non-LTEcorrection is practically determined by the parameters of theline-transition itself without any significant relevance to the detailsof the oxygen atomic model. This simplifies the problem in the sensethat the non-LTE abundance correction is essentially determined only bythe line-strength (Wlambda ), if the atmospheric parametersof Teff, log g, and xi are given, without any explicitdependence of the metallicity; thus allowing a useful analytical formulawith tabulated numerical coefficients. On the other hand, ourcalculations lead to the robust conclusion that LTE is totally valid forthe forbidden [O I] lines.An extensive reanalysis of published equivalent-width data of O I 7771-5and [O I] 6300/6363 taken from various literature resulted in theconclusion that, while a reasonable consistency of O I and [O I]abundances was observed for disk stars (-1 <~ [Fe/H] <~ 0), theexistence of a systematic abundance discrepancy was confirmed between OI and [O I] lines in conspicuously metal-poor halo stars (-3 <~[Fe/H] <~ -1) without being removed by our non-LTE corrections, i.e.,the former being larger by ~ 0.3 dex at -3 <~ [Fe/H] <~ -2.An inspection of the parameter-dependence of this discordance indicatesthat the extent of the discrepancy tends to be comparatively lessenedfor higher Teff/log g stars, suggesting the preference ofdwarf (or subgiant) stars for studying the oxygen abundances ofmetal-poor stars.Tables 2, 5, and 7 are only available in electronic form, at the CDS viaanonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/402/343 and Table\ref{tab3} is only available in electronic form athttp://www.edpsciences.org

Improved Astrometry and Photometry for the Luyten Catalog. II. Faint Stars and the Revised Catalog
We complete construction of a catalog containing improved astrometry andnew optical/infrared photometry for the vast majority of NLTT starslying in the overlap of regions covered by POSS I and by the secondincremental Two Micron All Sky Survey (2MASS) release, approximately 44%of the sky. The epoch 2000 positions are typically accurate to 130 mas,the proper motions to 5.5 mas yr-1, and the V-J colors to0.25 mag. Relative proper motions of binary components are measured to 3mas yr-1. The false-identification rate is ~1% for11<~V<~18 and substantially less at brighter magnitudes. Theseimprovements permit the construction of a reduced proper-motion diagramthat, for the first time, allows one to classify NLTT stars intomain-sequence (MS) stars, subdwarfs (SDs), and white dwarfs (WDs). We inturn use this diagram to analyze the properties of both our catalog andthe NLTT catalog on which it is based. In sharp contrast to popularbelief, we find that NLTT incompleteness in the plane is almostcompletely concentrated in MS stars, and that SDs and WDs are detectedalmost uniformly over the sky δ>-33deg. Our catalogwill therefore provide a powerful tool to probe these populationsstatistically, as well as to reliably identify individual SDs and WDs.

Vertical distribution of Galactic disk stars. I. Kinematics and metallicity
Nearly 400 Tycho-2 stars have been observed in a 720 square degree fieldin the direction of the North Galactic Pole with the high resolutionechelle spectrograph ELODIE. Absolute magnitudes, effectivetemperatures, gravities and metallicities have been estimated, as wellas distances and 3D velocities. Most of these stars are clump giants andspan typical distances from 200 pc to 800 pc to the galactic mid-plane.This new sample, free of any kinematical and metallicity bias, is usedto investigate the vertical distribution of disk stars. The old thindisk and thick disk populations are deconvolved from thevelocity-metallicity distribution of the sample and their parameters aredetermined. The thick disk is found to have a moderate rotational lag of-51 +/- 5 km s-1 with respect to the Sun with velocityellipsoid (sigmaU , sigmaV , sigmaW )=(63+/- 6, 39+/- 4, 39+/- 4) km s-1, mean metallicity of[Fe/H] = -0.48 +/- 0.05 and a high local normalization of 15 +/- 7%.Combining this NGP sample with a local sample of giant stars from theHipparcos catalogue, the orientation of the velocity ellipsoid isinvestigated as a function of distance to the plane and metallicity. Wefind no vertex deviation for old stars, consistent with an axisymmetricGalaxy. Paper II is devoted to the dynamical analysis of the sample,puting new constraints on the vertical force perpendicular to thegalactic plane and on the total mass density in the galactic plane.Based on observations made at the Observatoire de Haute Provence(France). Data are only available in electronic form at the CDS viaanonymous ftp to cdsarc.u-strasbg.fr (130.79.125.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/398/141

Abundances of Cu and Zn in metal-poor stars: Clues for Galaxy evolution
We present new observations of copper and zinc abundances in 90metal-poor stars, belonging to the metallicity range -3<[Fe/H]<-0.5. The present study is based on high resolutionspectroscopic measurements collected at the Haute Provence Observatoire(R= 42 000, S/N>100). The trend of Cu and Zn abundances as a functionof the metallicity [Fe/H] is discussed and compared to that of otherheavy elements beyond iron. We also estimate spatial velocities andgalactic orbital parameters for our target stars in order to disentanglethe population of disk stars from that of halo stars using kinematiccriteria. In the absence of a firm a priori knowledge of thenucleosynthesis mechanisms controlling Cu and Zn production, and of therelative stellar sites, we derive constraints on these last from thetrend of the observed ratios [Cu/Fe] and [Zn/Fe] throughout the historyof the Galaxy, as well as from a few well established properties ofbasic nucleosynthesis processes in stars. We thus confirm that theproduction of Cu and Zn requires a number of different sources (neutroncaptures in massive stars, s-processing in low and intermediate massstars, explosive nucleosynthesis in various supernova types). We alsoattempt a ranking of the relative roles played by different productionmechanisms, and verify these hints through a simple estimate of thegalactic enrichment in Cu and Zn. In agreement with suggestionspresented earlier, we find evidence that type Ia Supernovae must play arelevant role, especially for the production of Cu. Based on the spectracollected with the 1.93-m telescope of Haute Provence Observatory.

Chemical Abundances of Three Metal-poor Globular Clusters (NGC 6287, NGC 6293, and NGC 6541) in the Inner Halo
We present a chemical abundance study of three inner old halo clusters,NGC 6287, 6293, and 6541, finding [Fe/H]=-2.01+/-0.05, -1.99+/-0.02, and-1.76+/-0.02 (internal), respectively, and our metallicity measurementsare in good agreement with previous estimates. We also present theradial velocity measurements of the clusters. Our radial velocitymeasurements for NGC 6293 and NGC 6541 are in good agreement withprevious measurements; however, our radial velocity measurement for NGC6287 is almost 80 km s-1 larger than the previousmeasurement. The mean α-element abundances of our program clustersare in good agreement with other globular clusters, confirming previousresults. However, the individual α-elements appear to followdifferent trends. The silicon abundances of the inner halo clustersappear to be enhanced, and the titanium abundances appear to be depletedcompared to the intermediate halo clusters. Our results also appear tooppose to those of metal-rich bulge giants studied by McWilliam &Rich, who found that bulge giants are titanium-enhanced andsilicon-deficient. In particular, [Si/Ti] ratios appear to be related toGalactocentric distances, in the sense that [Si/Ti] ratios decrease withGalactocentric distance. We propose that contributions from differentmasses of the Type II supernovae progenitors that enrichedproto-globular cluster clouds' elemental abundances and the differentinitial physical environments surrounding the proto-globular clustersclouds are responsible for this gradient in [Si/Ti] ratios versusGalactocentric distances of the ``old halo'' globular clusters. On theother hand, our program clusters' enhanced s-process elementalabundances suggest that the formation timescale of our program clustersmight be as short as a few times 108 yr after the starformation is initiated in the Galaxy's central regions, if the s-processsite is intermediate-mass asymptotic giant branch stars.

Three-dimensional Spectral Classification of Low-Metallicity Stars Using Artificial Neural Networks
We explore the application of artificial neural networks (ANNs) for theestimation of atmospheric parameters (Teff, logg, and [Fe/H])for Galactic F- and G-type stars. The ANNs are fed withmedium-resolution (Δλ~1-2 Å) non-flux-calibratedspectroscopic observations. From a sample of 279 stars with previoushigh-resolution determinations of metallicity and a set of (external)estimates of temperature and surface gravity, our ANNs are able topredict Teff with an accuracy ofσ(Teff)=135-150 K over the range4250<=Teff<=6500 K, logg with an accuracy ofσ(logg)=0.25-0.30 dex over the range 1.0<=logg<=5.0 dex, and[Fe/H] with an accuracy σ([Fe/H])=0.15-0.20 dex over the range-4.0<=[Fe/H]<=0.3. Such accuracies are competitive with theresults obtained by fine analysis of high-resolution spectra. It isnoteworthy that the ANNs are able to obtain these results withoutconsideration of photometric information for these stars. We have alsoexplored the impact of the signal-to-noise ratio (S/N) on the behaviorof ANNs and conclude that, when analyzed with ANNs trained on spectra ofcommensurate S/N, it is possible to extract physical parameter estimatesof similar accuracy with stellar spectra having S/N as low as 13. Takentogether, these results indicate that the ANN approach should be ofprimary importance for use in present and future large-scalespectroscopic surveys.

New Analyses of Star-to-Star Abundance Variations among Bright Giants in the Mildly Metal-poor Globular Cluster M5
We present a chemical composition analysis of 36 giant stars in themildly metal-poor (<[Fe/H]>=-1.21) globular cluster M5 (NGC 5904).The analysis makes use of high-resolution data acquired for 25 stars atthe Keck I telescope, as well as a reanalysis of the high-resolutionspectra for 13 stars acquired for an earlier study at Lick Observatory.We employed two analysis techniques: (1) adopting standard spectroscopicconstraints, including setting the surface gravity from the ionizationequilibrium of iron, and (2) subsequent to investigating alternativeapproaches, adopting an analysis consistent with the non-LTE precepts asrecently described by Thévenin & Idiart. The abundance ratioswe derive for magnesium, silicon, calcium, scandium, titanium, vanadium,nickel, barium, and europium in M5 show no significant abundancevariations, and the ratios are comparable to those of halo field stars.However, large variations are seen in the abundances of oxygen, sodium,and aluminum, the elements that are sensitive to proton-capturenucleosynthesis. These variations are well-correlated with the CN bandstrength index S(3839). Surprisingly, in M5 the dependence of theabundance variations on logg is in the opposite sense to that discoveredin M13 by the Lick-Texas group where the relationship provided strongevidence in support of the evolutionary scenario. The present analysisof M5 giants does not necessarily rule out an evolutionary scenario, butit provides no support for it either. In comparing the abundances of M5and M4 (NGC 6121), another mildly metal-poor (<[Fe/H]>=-1.08)globular cluster, we find that silicon, aluminum, barium, and lanthanumare overabundant in M4 with respect to that seen in M5, confirming andexpanding the results of previous studies. In comparing the abundancesbetween these two clusters and others having comparable metallicities,we find that the anticorrelations observed in M5 are similar to thosefound in more metal-poor clusters, M3, M10, and M13 (<[Fe/H]>=-1.5to -1.6), whereas the behavior in M4 is more like that of the moremetal-rich globular cluster M71 (<[Fe/H]>~-0.8). We conclude thatamong stars in Galactic globular clusters there is no definitive``single'' value of [X/Fe] at a given [Fe/H] for at least some?-capture, odd-Z, and slow neutron-capture process elements, inthis case, silicon, aluminum, barium, and lanthanum. Based in part onobservations obtained with the W. M. Keck Observatory, which is operatedby the California Association for Research in Astronomy, Inc., on behalfof the University of California, the California Institute of Technology,and the National Aeronautics and Space Administration.

Catalogue of [Fe/H] determinations for FGK stars: 2001 edition
The catalogue presented here is a compilation of published atmosphericparameters (Teff, log g, [Fe/H]) obtained from highresolution, high signal-to-noise spectroscopic observations. This newedition has changed compared to the five previous versions. It is nowrestricted to intermediate and low mass stars (F, G and K stars). Itcontains 6354 determinations of (Teff, log g, [Fe/H]) for3356 stars, including 909 stars in 79 stellar systems. The literature iscomplete between January 1980 and December 2000 and includes 378references. The catalogue is made up of two tables, one for field starsand one for stars in galactic associations, open and globular clustersand external galaxies. The catalogue is distributed through the CDSdatabase. Access to the catalogue with cross-identification to othersets of data is also possible with VizieR (Ochsenbein et al.\cite{och00}). The catalogue (Tables 1 and 2) is only available inelectronic form at the CDS via anonymous ftp to cdsarc.u-strasbg.fr(130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/373/159 and VizieRhttp://vizier.u-strasbg.fr/.

Analysis of neutron capture elements in metal-poor stars
We derived model atmosphere parameters (Teff, log g, [Fe/H],Vt) for 90 metal-deficient stars (-0.5<[Fe/H]<-3),using echelle spectra from the ELODIE library (Soubiran et al.\cite{soubet98}). These parameters were analyzed and compared withcurrent determinations by other authors. The study of the followingelements was carried out: Mg, Si, Ca, Sr, Y, Ba, La, Ce, Nd, and Eu. Therelative contributions of s- and r-processes were evaluated andinterpreted through theoretical computations of the chemical evolutionof the Galaxy. The chemical evolution models (Pagel &Tautvaišienė \cite{pagta95}; Timmes et al. \cite{timet95})depict quite well the behaviour of [Si/Fe], [Ca/Fe] with [Fe/H]. Thetrend of [Mg/Fe] compares more favourably with the computations of Pagel& Tautvaišienė (\cite{pagta95}) than those of Timmes etal. (\cite{timet95}). The runs of n-capture elements vs. metallicity aredescribed well both by the model of Pagel & Tautvaišienė(\cite{pagta95}, \cite{pagta97}) and by the model of Travaglio et al.(\cite{travet99}) at [Fe/H]>-1.5, when the matter of the Galaxy issufficiently homogeneous. The analysis of n-capture element abundancesconfirms the jump in [Ba/Fe] at [Fe/H]=-2.5. Some stars from our sampleat [Fe/H]<-2.0 show a large scatter of Sr, Ba, Y, Ce. This scatter isnot caused by the errors in the measurements, and may reflect theinhomogeneous nature of the prestellar medium at early stages ofgalactic evolution. The matching of [Ba/Fe], [Eu/Fe] vs. [Fe/H] with theinhomogeneous model by Travaglio et al. (\cite{travet01a}) suggests thatat [Fe/H]<-2.5, the essential contribution to the n-rich elementabundances derives from the r-process. The main sources of theseprocesses may be low mass SN II. The larger dispersion of s-processelement abundances with respect to alpha -rich elements may arise bothfrom the birth of metal-poor stars in globular clusters with followingdifferent evolutionary paths and (or) from differences in s-elementenrichment in Galaxy populations. Based on spectra collected at theObservatoire de Haute-Provence (OHP), France

On the stellar content of the open clusters Melotte 105, Hogg 15, Pismis 21 and Ruprecht 140
CCD observations in the B, V and I passbands have been used to generatecolour-magnitude diagrams reaching down to V ~ 19 mag for two slightlycharacterized (Melotte 105 and Hogg 15) and two almost unstudied (Pismis21 and Ruprecht 140) open clusters. The sample consists of about 1300stars observed in fields of about 4arcmin x4arcmin . Our analysis showsthat neither Pismis 21 nor Ruprecht 140 are genuine open clusters sinceno clear main sequences or other meaningful features can be seen intheir colour-magnitude diagrams. Melotte 105 and Hogg 15 are openclusters affected by E(B-V) = 0.42 +/- 0.03 and 0.95 +/- 0.05,respectively. Their distances to the Sun have been estimated as 2.2 +/-0.3 and 2.6 +/- 0.08 kpc, respectively, while the corresponding agesestimated from empirical isochrones fitted to the Main Sequence clustermembers are ~ 350 Myr and 300 Myr, respectively. The present data arenot consistent with the membership of the WN6 star HDE 311884 to Hogg15. Tables 2 to 5 are only available in electronic form at the CDS viaanonymous ftp to cdsarc.u-strasbg.fr (130.793.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/370/931

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Observation and Astrometry data

Constellation:Serpens
Right ascension:18h09m40.69s
Declination:-08°46'45.6"
Apparent magnitude:8.168
Distance:307.692 parsecs
Proper motion RA:-95.9
Proper motion Dec:-190.4
B-T magnitude:9.285
V-T magnitude:8.261

Catalogs and designations:
Proper Names
HD 1989HD 166161
TYCHO-2 2000TYC 5676-339-1
USNO-A2.0USNO-A2 0750-12752190
HIPHIP 88977

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