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Characterizing the Chemistry of the Milky Way Stellar Halo: Detailed Chemical Analysis of a Metal-poor Stellar Stream
We present the results of a detailed abundance analysis of one of theconfirmed building blocks of the Milky Way stellar halo, a kinematicallycoherent metal-poor stellar stream. We have obtained high-resolution andhigh signal-to-noise spectra of 12 probable stream members using theMagellan Inamori Kyocera Echelle spectrograph on the Magellan-ClayTelescope at Las Campanas Observatory and the 2dCoude spectrograph onthe Smith Telescope at McDonald Observatory. We have derived abundancesor upper limits for 51 species of 46 elements in each of these stars.The stream members show a range of metallicity (-3.4 < [Fe/H]<-1.5) but are otherwise chemically homogeneous, with the samestar-to-star dispersion in [X/Fe] as the rest of the halo. This impliesthat, in principle, a significant fraction of the Milky Way stellar halocould have formed from accreted systems like the stream. The streamstars show minimal evolution in the ? or Fe-group elements overthe range of metallicity. This stream is enriched with material producedby the main and weak components of the rapid neutron-capture process andshows no evidence for enrichment by the slow neutron-capture process.This paper includes data gathered with the 6.5 m Magellan Telescopeslocated at Las Campanas Observatory, Chile.This paper includes data taken at The McDonald Observatory of theUniversity of Texas at Austin.

Chemical Abundances of Outer Halo Stars in the Milky Way
We present the chemical abundances of 57 metal-poor ([Fe/H] 5 kpc above andbelow the Galactic plane. High-resolution (R ˜ 50000-55000), highsignal-to-noise (S/N > 100) spectra for the sample stars obtainedwith Subaru/HDS were used to derive the chemical abundances of Na, Mg,Ca, Ti, Cr, Mn, Fe, Ni, Zn, Y, and Ba with an LTE abundance analysiscode. The resulting abundance data were combined with those presented inthe literature that mostly targeted at smaller Zmax stars,and both data were used to investigate any systematic trends in detailedabundance patterns depending on their kinematics. It was shown that, inthe metallicity range of ?2 < [Fe/H] < ?1, the [Mg/Fe]ratios for stars with Zmax > 5 kpc are systematicallylower (˜0.1 dex) than those with a smaller Zmax. Forthis metallicity range, a modest degree of depression in the [Si/Fe] andthe [Ca/Fe] ratios was also observed. This result of lower [?/Fe]for the assumed outer halo stars is consistent with previous studiesthat found a signature of lower [?/Fe] ratios for stars withextreme kinematics. The distribution of the [Mg/Fe] ratios for the outerhalo stars partly overlaps with that for stars belonging to the MilkyWay dwarf satellites in the metallicity interval of ?2 < [Fe/H]< ?1 and spans a range intermediate between the distributionsfor the inner halo stars and the stars belonging to the satellites. Ourresults confirm the inhomogeneous nature of the chemical abundanceswithin the Milky Way stellar halo, depending on the kinematic propertiesof the constituent stars, as suggested by earlier studies. Possibleimplications for the formation of the Milky Way halo and its relevanceto the suggested dual nature of the halo are discussed.

Chemical Compositions of Kinematically Selected Outer Halo Stars
Chemical abundances of 26 metal-poor dwarfs and giants are determinedfrom high-resolution and high signal-to-noise ratio spectra obtainedwith the Subaru/High Dispersion Spectrograph. The sample is selected sothat most of the objects have outer-halo kinematics. Self-consistentatmospheric parameters were determined by an iterative procedure basedon spectroscopic analysis. Abundances of 13 elements, includingα-elements (Mg, Si, Ca, Ti), odd-Z light elements (Na, Sc),iron-peak elements (Cr, Mn, Fe, Ni, Zn), and neutron-capture elements(Y, Ba), are determined by two independent data reduction and localthermodynamic equillibrium analysis procedures, confirming theconsistency of the stellar parameters and abundances results. We find adecreasing trend of [α/Fe] with increasing [Fe/H] for the range of–3.5< [Fe/H] <–1, as found by Stephens &Boesgaard. [Zn/Fe] values of most objects in our sample are slightlylower than the bulk of halo stars previously studied. These results arediscussed as possible chemical properties of the outer halo in theGalaxy.Based on data collected at the Subaru Telescope, which is operated bythe National Astronomical Observatory of Japan.

An Overview of the Rotational Behavior of Metal-poor Stars
This paper describes the behavior of the rotational velocity inmetal-poor stars ([Fe/H] <= -0.5 dex) in different evolutionarystages, based on vsin i values from the literature. Our sample iscomprised of stars in the field and some Galactic globular clusters,including stars on the main sequence, the red giant branch (RGB), andthe horizontal branch (HB). The metal-poor stars are, mainly, slowrotators, and their vsin i distribution along the HR diagram is quitehomogeneous. Nevertheless, a few moderate to high values of vsin i arefound in stars located on the main sequence and the HB. We show that theoverall distribution of vsin i values is basically independent ofmetallicity for the stars in our sample. In particular, thefast-rotating main sequence stars in our sample present rotation ratessimilar to their metal-rich counterparts, suggesting that some of themmay actually be fairly young, in spite of their low metallicity, or elsethat at least some of them would be better classified as blue stragglerstars. We do not find significant evidence of evolution in vsin i valuesas a function of position on the RGB; in particular, we do not confirmprevious suggestions that stars close to the RGB tip rotate faster thantheir less-evolved counterparts. While the presence of fast rotatorsamong moderately cool blue HB stars has been suggested to be due toangular momentum transport from a stellar core that has retainedsignificant angular momentum during its prior evolution, we find thatany such transport mechanisms most likely operate very fast as the stararrives on the zero-age HB (ZAHB), since we do not find a link betweenevolution off the ZAHB and vsin i values. We present an extensivetabulation of all quantities discussed in this paper, including rotationvelocities, temperatures, gravities, and metallicities [Fe/H], as wellas broadband magnitudes and colors.

The Geneva-Copenhagen survey of the solar neighbourhood. III. Improved distances, ages, and kinematics
Context: Ages, chemical compositions, velocity vectors, and Galacticorbits for stars in the solar neighbourhood are fundamental test datafor models of Galactic evolution. The Geneva-Copenhagen Survey of theSolar Neighbourhood (Nordström et al. 2004; GCS), amagnitude-complete, kinematically unbiased sample of 16 682 nearby F andG dwarfs, is the largest available sample with complete data for starswith ages spanning that of the disk. Aims: We aim to improve theaccuracy of the GCS data by implementing the recent revision of theHipparcos parallaxes. Methods: The new parallaxes yield improvedastrometric distances for 12 506 stars in the GCS. We also use theparallaxes to verify the distance calibration for uvby? photometryby Holmberg et al. (2007, A&A, 475, 519; GCS II). We add newselection criteria to exclude evolved cool stars giving unreliableresults and derive distances for 3580 stars with large parallax errorsor not observed by Hipparcos. We also check the GCS II scales of T_effand [Fe/H] and find no need for change. Results: Introducing thenew distances, we recompute MV for 16 086 stars, and U, V, W,and Galactic orbital parameters for the 13 520 stars that also haveradial-velocity measurements. We also recompute stellar ages from thePadova stellar evolution models used in GCS I-II, using the new valuesof M_V, and compare them with ages from the Yale-Yonsei andVictoria-Regina models. Finally, we compare the observed age-velocityrelation in W with three simulated disk heating scenarios to show thepotential of the data. Conclusions: With these revisions, thebasic data for the GCS stars should now be as reliable as is possiblewith existing techniques. Further improvement must await consolidationof the T_eff scale from angular diameters and fluxes, and the Gaiatrigonometric parallaxes. We discuss the conditions for improvingcomputed stellar ages from new input data, and for distinguishingdifferent disk heating scenarios from data sets of the size andprecision of the GCS.Full Table 1 is only available in electronic form at the CDS viaanonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/501/941

The End of Nucleosynthesis: Production of Lead and Thorium in the Early Galaxy
We examine the Pb and Th abundances in 27 metal-poor stars(-3.1< [Fe/H] <-1.4) whose very heavy metal (Z >56) enrichment was produced only by the rapid (r-) nucleosynthesisprocess. New abundances are derived from Hubble Space Telescope/SpaceTelescope Imaging Spectrograph, Keck/High Resolution EchelleSpectrograph, and Very Large Telescope/UV-Visual Echelle Spectrographspectra and combined with other measurements from the literature to forma more complete picture of nucleosynthesis of the heaviest elementsproduced in the r-process. In all cases, the abundance ratios among therare earth elements and the third r-process peak elements considered(La, Eu, Er, Hf, and Ir) are constant and equivalent to the scaled solarsystem r-process abundance distribution. We compare the stellarobservations with r-process calculations within the classical"waiting-point" approximation. In these computations a superposition of15 weighted neutron-density components in the range 23 <=lognn <= 30 is fit to the r-process abundance peaks tosuccessfully reproduce both the stable solar system isotopicdistribution and the stable heavy element abundance pattern between Baand U in low-metallicity stars. Under these astrophysical conditions,which are typical of the "main" r-process, we find very good agreementbetween the stellar Pb r-process abundances and those predicted by ourmodel. For stars with anomalously high Th/Eu ratios (the so-calledactinide boost), our observations demonstrate that any nucleosyntheticdeviations from the main r-process affect—at most—only theelements beyond the third r-process peak, namely Pb, Th, and U. Ourtheoretical calculations also indicate that possible r-process abundance"losses" by nuclear fission are negligible for isotopes along ther-process path between Pb and the long-lived radioactive isotopes of Thand U.

Beryllium abundances and star formation in the halo and in the thick disk
Context: Beryllium is a pure product of cosmic ray spallation. Thisimplies a relatively simple evolution in time of the beryllium abundanceand suggests its use as a time-like observable. Aims: Our goal is toderive abundances of Be in a sample of 90 stars, the largest sample ofhalo and thick disk stars analyzed to date. We study the evolution of Bein the early Galaxy and its dependence on kinematic and orbitalparameters, and investigate its use as a cosmochronometer. Abundances ofBe, Fe, and α-elements of 73 stars are employed to study theformation of the halo and the thick disk of the Galaxy. Methods:Beryllium abundances are determined from high-resolution, highsignal-to-noise UVES spectra with spectrum synthesis. Atmosphericparameters and abundances of α-elements are adopted from theliterature. Lithium abundances are used to eliminate mixed stars fromthe sample. The properties of halo and thick disk stars are investigatedin diagrams of log(Be/H) vs. [ α/H] , log(Be/H) vs. [Fe/H], and [α/Fe] vs. log(Be/H) and with orbital and kinematic parameters. Results: We present our observational results in various diagrams. (i)In a log(Be/H) vs. [Fe/H] diagram we find a marginal statisticaldetection of a real scatter, above what is expected from measurementerrors, with a larger scatter among halo stars. The detection of thescatter is further supported by the existence of pairs of stars withidentical atmospheric parameters and different Be abundances; (ii) in alog(Be/H) vs. [ α/Fe] diagram, the halo stars separate into twocomponents; one is consistent with predictions of evolutionary models,while the other has too high α and Be abundances and is chemicallyindistinguishable from thick disk stars. This suggests that the halo isnot a single uniform population where a clear age-metallicity relationcan be defined; (iii) In diagrams of R_min vs. [ α/Fe] andlog(Be/H), the thick disk stars show a possible decrease in [α/Fe] with R_min, whereas no dependence of Be with R_min is seen.This anticorrelation suggests that the star formation rate was lower inthe outer regions of the thick disk, pointing towards an inside-outformation. The lack of correlation for Be indicates that it isinsensitive to the local conditions of star formation.Based on observations made with ESO VLT, at Paranal Observatory, underprograms 076.B-0133 and 077.B-0507, and on data obtained from theESO/ST-ECF Science Archive Facility and the UVES Paranal ObservatoryProject 266.D-5655.Tables 1-3, 6 and Appendices A-C are only available in electronic format http://www.aanda.org

Calibration of Strömgren uvby-H? photometry for late-type stars - a model atmosphere approach
Context: The use of model atmospheres for deriving stellar fundamentalparameters, such as T_eff, log g, and [Fe/H], will increase as we findand explore extreme stellar populations where empirical calibrations arenot yet available. Moreover, calibrations for upcoming large satellitemissions of new spectrophotometric indices, similar to the uvby-H?system, will be needed. Aims: We aim to test the power oftheoretical calibrations based on a new generation of MARCS models bycomparisons with observational photomteric data. Methods: Wecalculated synthetic uvby-H? colour indices from synthetic spectra.A sample of 367 field stars, as well as stars in globular clusters, isused for a direct comparison of the synthetic indices versus empiricaldata and for scrutinizing the possibilities of theoretical calibrationsfor temperature, metallicity, and gravity. Results: We show thatthe temperature sensitivity of the synthetic (b-y) colour is very closeto its empirical counterpart, whereas the temperature scale based uponH? shows a slight offset. The theoretical metallicity sensitivityof the m1 index (and for G-type stars its combination withc_1) is somewhat higher than the empirical one, based upon spectroscopicdeterminations. The gravity sensitivity of the synthetic c1index shows satisfactory behaviour when compared to obervations of Fstars. For stars cooler than the sun, a deviation is significant in thec1-(b-y) diagram. The theoretical calibrations of (b-y),(v-y), and c1 seem to work well for Pop II stars and lead toeffective temperatures for globular cluster stars supporting recentclaims that atomic diffusion occurs in stars near the turnoff point ofNGC 6397. Conclusions: Synthetic colours of stellar atmospherescan indeed be used, in many cases, to derive reliable fundamentalstellar parameters. The deviations seen when compared to observationaldata could be due to incomplete linelists but are possibly also due tothe effects of assuming plane-parallell or spherical geometry and LTE.Model colours are only available in electronic form at the CDS viaanonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/498/527

Taking Another Look: Light n-Capture Element Abundances in Metal-Poor Halo Stars
Elements are produced in stars through a variety of processes; some arewell known, others are still the object of active research. The elementszirconium (Zr) and yttrium (Y) reside in the mass range where there isuncertainty about the production mechanism at early time. The rapidn-capture elements.

Line Broadening in Field Metal-Poor Red Giant and Red Horizontal Branch Stars
We report 349 radial velocities for 45 metal-poor field red giant branch(RGB) and red horizontal branch (RHB) stars, with time coverage rangingfrom 1 to 21 years. We have identified one new spectroscopic binary, HD4306, and one possible such system, HD 184711. We also provide 57 radialvelocities for 11 of the 91 stars reported in our previous work. All butone of the 11 stars had been found to have variable radial velocities.New velocities for the long-period spectroscopic binaries BD-1 2582 andHD 108317 have extended the time coverage to 21.7 and 12.5 years,respectively, but in neither case have we yet completed a full orbitalperiod. As was found in the previous study, radial velocity "jitter" ispresent in many of the most luminous stars. Excluding stars showingspectroscopic binary orbital motion, all 7 of the red giants withestimated MV values more luminous than -2.0 display jitter,as well as 3 of the 14 stars with -2.0 < MV <= -1.4. Wehave also measured the line broadening in all the new spectra, usingsynthetic spectra as templates. Comparison with results fromhigh-resolution and higher signal-to-noise (S/N) spectra employed byother workers shows good agreement down to line-broadening levels of 3km s-1, well below our instrumental resolution of 8.5 kms-1. As the previous work demonstrated, the majority of themost luminous red giants show significant line broadening, as do many ofthe red horizontal branch stars, and we briefly discuss possible causes.The line broadening appears related to velocity jitter, in that bothappear primarily among the highest luminosity red giants.

Strömgren Photometry of Galactic Globular Clusters. I. New Calibrations of the Metallicity Index
We present a new calibration of the Strömgren metallicity indexm1 using red giant (RG) stars in four globular clusters (GCs:M92, M13, NGC 1851, 47 Tuc) with metallicity ranging from -2.2 to -0.7,marginally affected by reddening [E(B-V)<=0.04] and with accurate(u,v,b,y) photometry. The main difference between the newmetallicity-index-color (MIC) relations and similar relations availablein the literature is that we have adopted the u-y and v-y colors insteadof b-y. These colors present a stronger sensitivity to effectivetemperature, and the MIC relations show a linear slope. The differencebetween photometric estimates and spectroscopic measurements for RGs inM71, NGC 288, NGC 362, NGC 6397, and NGC 6752 is 0.04+/-0.03 dex(σ=0.11 dex). We also apply the new MIC relations to 85 field RGswith metallicity ranging from -2.4 to -0.5 and accurate reddeningestimates. We find that the difference between photometric estimates andspectroscopic measurements is -0.14+/-0.01 dex (σ=0.17 dex). Wealso provide two sets of MIC relations based on evolutionary models thathave been transformed into the observational plane by adopting eithersemiempirical or theoretical color-temperature relations. We apply thesemiempirical relations to the nine GCs and find that the differencebetween photometric and spectroscopic metallicities is 0.04+/-0.03 dex(σ=0.10 dex). A similar agreement is found for the sample of fieldRGs, with a difference of -0.09+/-0.03 dex (with σ=0.19 dex). Thedifference between metallicity estimates based on theoretical relationsand spectroscopic measurements is -0.11+/-0.03 dex (σ=0.14 dex)for the nine GCs and -0.24+/-0.03 dex (σ=0.15 dex) for the fieldRGs. Current evidence indicates that new MIC relations providemetallicities with an intrinsic accuracy better than 0.2 dex.Based in part on observations collected with the 1.54 m Danish Telescopeoperated at ESO (La Silla, Chile) and with the Nordic Optical Telescope(NOT) operated at La Palma (Spain).

Halo Star Streams in the Solar Neighborhood
We have assembled a sample of halo stars in the solar neighborhood tolook for halo substructure in velocity and angular momentum space. Oursample (231 stars) includes red giants, RR Lyrae variable stars, and redhorizontal branch stars within 2.5 kpc of the Sun with [Fe/H] less than-1.0. It was chosen to include stars with accurate distances, spacevelocities, and metallicities, as well as well-quantified errors. Withour data set, we confirm the existence of the streams found by Helmi andcoworkers, which we refer to as the H99 streams. These streams have adouble-peaked velocity distribution in the z-direction (out of theGalactic plane). We use the results of modeling of the H99 streams byHelmi and collaborators to test how one might use vz velocityinformation and radial velocity information to detect kinematicsubstructure in the halo. We find that detecting the H99 streams withradial velocities alone would require a large sample (e.g.,approximately 150 stars within 2 kpc of the Sun and within 20° ofthe Galactic poles). In addition, we use the velocity distribution ofthe H99 streams to estimate their age. From our model of the progenitorof the H99 streams, we determine that it was accreted between 6 and 9Gyr ago. The H99 streams have [α/Fe] abundances similar to otherhalo stars in the solar neighborhood, suggesting that the gas thatformed these stars were enriched mostly by Type II supernovae. We havealso discovered in angular momentum space two other possiblesubstructures, which we refer to as the retrograde and progradeoutliers. The retrograde outliers are likely to be halo substructure,but the prograde outliers are most likely part of the smooth halo. Theretrograde outliers have significant structure in the vφdirection and show a range of [α/Fe], with two having low[α/Fe] for their [Fe/H]. The fraction of substructure stars in oursample is between 5% and 7%. The methods presented in this paper can beused to exploit the kinematic information present in future largedatabases like RAVE, SDSS-II/SEGUE, and Gaia.

Measuring the Balmer Jump and the Effective Gravity in FGK Stars
It is difficult to accurately measure the effective gravity (logg) inlate-type stars using broadband (e.g., UBV or SDSS) or intermediate-band(uvby) photometric systems, especially when the stars can cover a rangeof metallicities and reddenings. However, simple spectroscopicobservational and data reduction techniques can yield accurate valuesfor logg through comparison of the Balmer jumps of low-resolutionspectra with recent grids of synthetic flux spectra.

Pulkovo compilation of radial velocities for 35495 stars in a common system.
Not Available

A catalog of rotational and radial velocities for evolved stars. IV. Metal-poor stars^
Aims.The present paper describes the first results of an observationalprogram intended to refine and extend the existing v sin i measurementsof metal-poor stars, with an emphasis on field evolved stars.Methods: .The survey was carried out with the FEROS and CORALIEspectrometers. For the v sin i measurements, obtained from spectralsynthesis, we estimate an uncertainty of about 2.0 km s-1. Results: .Precise rotational velocities v sin i are presented for alarge sample of 100 metal-poor stars, most of them evolving off themain-sequence. For the large majority of the stars composing the presentsample, rotational velocities have been measured for the first time.

Oxygen abundances in metal-poor subgiants as determined from [O I], O I and OH lines
The debate on the oxygen abundances of metal-poor stars has its originin contradictory results obtained using different abundance indicators.To achieve a better understanding of the problem we have acquired highquality spectra with the Ultraviolet and Visual Echelle Spectrograph atVLT, with a signal-to-noise of the order of 100 in the near ultravioletand 500 in the optical and near infrared wavelength range. Threedifferent oxygen abundance indicators, OH ultraviolet lines around 310.0nm, the [O i] line at 630.03 nm and the O i lines at 777.1-5 nm wereobserved in the spectra of 13 metal-poor subgiants with-3.0≤[Fe/H]≤-1.5. Oxygen abundances were obtained from theanalysis of these indicators which was carried out assuming localthermodynamic equilibrium and plane-parallel model atmospheres.Abundances derived from O i were corrected for departures from localthermodynamic equilibrium. Stellar parameters were computed usingT_eff-vs.-color calibrations based on the infrared flux method andBalmer line profiles, Hipparcos parallaxes and Fe II lines. [O/Fe]values derived from the forbidden line at 630.03 nm are consistent withan oxygen/iron ratio that varies linearly with [Fe/H] as[O/Fe]=-0.09(±0.08)[Fe/H]+0.36(±0.15). Values based on theO i triplet are on average 0.19±0.22 dex(s.d.) higher than thevalues based on the forbidden line while the agreement between OHultraviolet lines and the forbidden line is much better with a meandifference of the order of -0.09±0.25 dex(s.d.). In general, ourresults follow the same trend as previously published results with theexception of the ones based on OH ultraviolet lines. In that case ourresults lie below the values which gave rise to the oxygen abundancedebate for metal-poor stars.

Li and Be depletion in metal-poor subgiants
A sample of metal-poor subgiants has been observed with the UVESspectrograph at the Very Large Telescope and abundances of Li and Behave been determined. Typical signal-to-noise per spectral bin valuesfor the co-added spectra are of the order of 500 for the ion{Li}{i} line(670.78 nm) and 100 for the ion{Be}{ii} doublet lines (313.04 nm). Thespectral analysis of the observations was carried out using the Uppsalasuite of codes and marcs (1D-LTE) model atmospheres with stellarparameters from photometry, parallaxes, isochrones and Fe ii lines.Abundance estimates of the light elements were corrected for departuresfrom local thermodynamic equilibrium in the line formation. Effectivetemperatures and Li abundances seem to be correlated and Be abundancescorrelate with [O/H]. Standard models predict Li and Be abundancesapproximately one order of magnitude lower than main-sequence valueswhich is in general agreement with the observations. On average, ourobserved depletions seem to be 0.1 dex smaller and between 0.2 and 0.4dex larger (depending on which reference is taken) than those predictedfor Li and Be, respectively. This is not surprising since the initial Liabundance, as derived from main-sequence stars on the Spite plateau, maybe systematically in error by 0.1 dex or more, and uncertainties in thespectrum normalisation and continuum drawing may affect our Beabundances systematically.

Estimation of Carbon Abundances in Metal-Poor Stars. I. Application to the Strong G-Band Stars of Beers, Preston, and Shectman
We develop and test a method for the estimation of metallicities([Fe/H]) and carbon abundance ratios ([C/Fe]) for carbon-enhancedmetal-poor (CEMP) stars based on the application of artificial neuralnetworks, regressions, and synthesis models to medium-resolution (1-2Å) spectra and J-K colors. We calibrate this method by comparisonwith metallicities and carbon abundance determinations for 118 starswith available high-resolution analyses reported in the recentliterature. The neural network and regression approaches make use of apreviously defined set of line-strength indices quantifying the strengthof the Ca II K line and the CH G band, in conjunction with J-K colorsfrom the Two Micron All Sky Survey Point Source Catalog. The use ofnear-IR colors, as opposed to broadband B-V colors, is required becauseof the potentially large affect of strong molecular carbon bands onbluer color indices. We also explore the practicality of obtainingestimates of carbon abundances for metal-poor stars from the spectralinformation alone, i.e., without the additional information provided byphotometry, as many future samples of CEMP stars may lack such data. Wefind that although photometric information is required for theestimation of [Fe/H], it provides little improvement in our derivedestimates of [C/Fe], and hence, estimates of carbon-to-iron ratios basedsolely on line indices appear sufficiently accurate for most purposes.Although we find that the spectral synthesis approach yields the mostaccurate estimates of [C/Fe], in particular for the stars with thestrongest molecular bands, it is only marginally better than is obtainedfrom the line index approaches. Using these methods we are able toreproduce the previously measured [Fe/H] and [C/Fe] determinations withan accuracy of ~0.25 dex for stars in the metallicity interval-5.5<=[Fe/H]<=-1.0 and with 0.2<=(J-K)0<=0.8. Athigher metallicity, the Ca II K line begins to saturate, especially forthe cool stars in our program, and hence, this approach is not useful insome cases. As a first application, we estimate the abundances of [Fe/H]and [C/Fe] for the 56 stars identified as possibly carbon-rich, relativeto stars of similar metal abundance, in the sample of ``strong G-band''stars discussed by Beers, Preston, and Shectman.

The lithium content of the Galactic Halo stars
Thanks to the accurate determination of the baryon density of theuniverse by the recent cosmic microwave background experiments, updatedpredictions of the standard model of Big Bang nucleosynthesis now yieldthe initial abundance of the primordial light elements withunprecedented precision. In the case of ^7Li, the CMB+SBBN value issignificantly higher than the generally reported abundances for Pop IIstars along the so-called Spite plateau. In view of the crucialimportance of this disagreement, which has cosmological, galactic andstellar implications, we decided to tackle the most critical issues ofthe problem by revisiting a large sample of literature Li data in halostars that we assembled following some strict selection criteria on thequality of the original analyses. In the first part of the paper wefocus on the systematic uncertainties affecting the determination of theLi abundances, one of our main goal being to look for the "highestobservational accuracy achievable" for one of the largest sets of Liabundances ever assembled. We explore in great detail the temperaturescale issue with a special emphasis on reddening. We derive four sets ofeffective temperatures by applying the same colour {T}_eff calibrationbut making four different assumptions about reddening and determine theLTE lithium values for each of them. We compute the NLTE corrections andapply them to the LTE lithium abundances. We then focus on our "best"(i.e. most consistent) set of temperatures in order to discuss theinferred mean Li value and dispersion in several {T}_eff and metallicityintervals. The resulting mean Li values along the plateau for [Fe/H]≤ 1.5 are A(Li)_NLTE = 2.214±0.093 and 2.224±0.075when the lowest effective temperature considered is taken equal to 5700K and 6000 K respectively. This is a factor of 2.48 to 2.81 (dependingon the adopted SBBN model and on the effective temperature range chosento delimit the plateau) lower than the CMB+SBBN determination. We findno evidence of intrinsic dispersion. Assuming the correctness of theCMB+SBBN prediction, we are then left with the conclusion that the Liabundance along the plateau is not the pristine one, but that halo starshave undergone surface depletion during their evolution. In the secondpart of the paper we further dissect our sample in search of newconstraints on Li depletion in halo stars. By means of the Hipparcosparallaxes, we derive the evolutionary status of each of our samplestars, and re-discuss our derived Li abundances. A very surprisingresult emerges for the first time from this examination. Namely, themean Li value as well as the dispersion appear to be lower (althoughfully compatible within the errors) for the dwarfs than for the turnoffand subgiant stars. For our most homogeneous dwarfs-only sample with[Fe/H] ≤ 1.5, the mean Li abundances are A(L)_NLTE = 2.177±0.071 and 2.215±0.074 when the lowest effective temperatureconsidered is taken equal to 5700 K and 6000 K respectively. This is afactor of 2.52 to 3.06 (depending on the selected range in {T}_eff forthe plateau and on the SBBN predictions we compare to) lower than theCMB+SBBN primordial value. Instead, for the post-main sequence stars thecorresponding values are 2.260±0.1 and 2.235±0.077, whichcorrespond to a depletion factor of 2.28 to 2.52. These results,together with the finding that all the stars with Li abnormalities(strong deficiency or high content) lie on or originate from the hotside of the plateau, lead us to suggest that the most massive of thehalo stars have had a slightly different Li history than their lessmassive contemporaries. In turn, this puts strong new constraints on thepossible depletion mechanisms and reinforces Li as a stellartomographer.

Chemical abundances in 43 metal-poor stars
We have derived abundances of O, Na, Mg, Al, Si, Ca, Sc, Ti, V, Cr, Fe,Ni, and Ba for 43 metal-poor field stars in the solar neighbourhood,most of them subgiants or turn-off-point stars with iron abundances[Fe/H] ranging from -0.4 to -3.0. About half of this sample has not beenspectroscopically analysed in detail before. Effective temperatures wereestimated from uvby photometry, and surface gravities primarily fromHipparcos parallaxes. The analysis is differential relative to the Sun,and was carried out with plane-parallel MARCS models. Various sources oferror are discussed and found to contribute a total error of about0.1-0.2 dex for most elements, while relative abundances, such as[Ca/Fe], are most probably more accurate. For the oxygen abundances,determined in an NLTE analysis of the 7774 Å triplet lines, theerrors may be somewhat larger. We made a detailed comparison withsimilar studies and traced the reasons for the, in most cases,relatively small differences. Among the results we find that [O/Fe]possibly increases beyond [Fe/H] = -1.0, though considerably less sothan in results obtained by others from abundances based on OH lines. Wedid not trace any tendency toward strong overionization of iron, andfind the excesses, relative to Fe and the Sun, of the α elementsMg, Si, and Ca to be smaller than those of O. We discuss someindications that also the abundances of different α elementsrelative to Fe vary and the possibility that some of the scatter aroundthe trends in abundances relative to iron may be real. This may supportthe idea that the formation of Halo stars occurred in smaller systemswith different star formation rates. We verify the finding by Gratton etal. (2003b, A&A, 406, 131) that stars that do not participate in therotation of the galactic disk show a lower mean and larger spread in [α/Fe] than stars participating in the general rotation. The latterstars also seem to show some correlation between [ α/Fe] androtation speed. We trace some stars with peculiar abundances, amongthese two Ba stars, HD 17072 and HD196944, the second already known to be rich in s elements.Finally we advocate that a spectroscopic study of a larger sample ofhalo stars with well-defined selection criteria is very important, inorder to add to the very considerable efforts that various groups havealready made.

Structure in the motions of the fastest halo stars
We analyzed the catalog published by Beers et al. (2000, ApJ, 119, 2866)of 2106 non-kinematically selected metal poor stars in the solarneighborhood, with the goal of quantifying the amount of substructure inthe motions of the fastest halo stars. We computed the two-pointvelocity correlation function for a subsample of halo stars within 1-2kpc of the Sun, and found statistical evidence of substructure with asimilar amplitude to that predicted by high resolution CDM simulations.The signal is due to a small kinematic group whose dynamical propertiesare compared to the stellar "stream" previously discovered by Helmi etal. (1999). If real, this high velocity moving group would providefurther support for the idea that substructures remain as fossils fromthe formation of the Galaxy as expected in the CDM scenario.

The Rise of the s-Process in the Galaxy
From newly obtained high-resolution, high signal-to-noise ratio spectrathe abundances of the elements La and Eu have been determined over thestellar metallicity range -3<[Fe/H]<+0.3 in 159 giant and dwarfstars. Lanthanum is predominantly made by the s-process in the solarsystem, while Eu owes most of its solar system abundance to ther-process. The changing ratio of these elements in stars over a widemetallicity range traces the changing contributions of these twoprocesses to the Galactic abundance mix. Large s-process abundances canbe the result of mass transfer from very evolved stars, so to identifythese cases we also report carbon abundances in our metal-poor stars.Results indicate that the s-process may be active as early as[Fe/H]=-2.6, although we also find that some stars as metal-rich as[Fe/H]=-1 show no strong indication of s-process enrichment. There is asignificant spread in the level of s-process enrichment even at solarmetallicity.

Subgiants as probes of galactic chemical evolution
Chemical abundances for 23 candidate subgiant stars have been derivedwith the aim at exploring their usefulness for studies of galacticchemical evolution. High-resolution spectra from ESO CAT-CES andNOT-SOFIN covered 16 different spectral regions in the visible part ofthe spectrum. Some 200 different atomic and molecular spectral lineshave been used for abundance analysis of ˜30 elemental species. Thewings of strong, pressure-broadened metal lines were used fordetermination of stellar surface gravities, which have been comparedwith gravities derived from HIPPARCOS parallaxes and isochronic masses.Stellar space velocities have been derived from HIPPARCOS and Simbaddata, and ages and masses were derived with recent isochrones. Only 12of the stars turned out to be subgiants, i.e. on the ``horizontal'' partof the evolutionary track between the dwarf- and the giant stages. Theabundances derived for the subgiants correspond closely to those ofdwarf stars. With the possible exceptions of lithium and carbon we findthat subgiant stars show no ``chemical'' traces of post-main-sequenceevolution and that they are therefore very useful targets for studies ofgalactic chemical evolution.Based on observations made at ESO, La Silla.Based on observations made at NOT, La Palma.Tables 1 and 2 are only available in electronic form athttp://www.edpsciences.org

Stellar Chemical Signatures and Hierarchical Galaxy Formation
To compare the chemistries of stars in the Milky Way dwarf spheroidal(dSph) satellite galaxies with stars in the Galaxy, we have compiled alarge sample of Galactic stellar abundances from the literature. Whenkinematic information is available, we have assigned the stars tostandard Galactic components through Bayesian classification based onGaussian velocity ellipsoids. As found in previous studies, the[α/Fe] ratios of most stars in the dSph galaxies are generallylower than similar metallicity Galactic stars in this extended sample.Our kinematically selected stars confirm this for the Galactic halo,thin-disk, and thick-disk components. There is marginal overlap in thelow [α/Fe] ratios between dSph stars and Galactic halo stars onextreme retrograde orbits (V<-420 km s-1), but this is notsupported by other element ratios. Other element ratios compared in thispaper include r- and s-process abundances, where we find a significantoffset in the [Y/Fe] ratios, which results in a large overabundance in[Ba/Y] in most dSph stars compared with Galactic stars. Thus, thechemical signatures of most of the dSph stars are distinct from thestars in each of the kinematic components of the Galaxy. This resultrules out continuous merging of low-mass galaxies similar to these dSphsatellites during the formation of the Galaxy. However, we do not ruleout very early merging of low-mass dwarf galaxies, since up to one-halfof the most metal-poor stars ([Fe/H]<=-1.8) have chemistries that arein fair agreement with Galactic halo stars. We also do not rule outmerging with higher mass galaxies, although we note that the LMC and theremnants of the Sgr dwarf galaxy are also chemically distinct from themajority of the Galactic halo stars. Formation of the Galaxy's thickdisk by heating of an old thin disk during a merger is also not ruledout; however, the Galaxy's thick disk itself cannot be comprised of theremnants from a low-mass (dSph) dwarf galaxy, nor of a high-mass dwarfgalaxy like the LMC or Sgr, because of differences in chemistry.The new and independent environments offered by the dSph galaxies alsoallow us to examine fundamental assumptions related to thenucleosynthesis of the elements. The metal-poor stars ([Fe/H]<=-1.8)in the dSph galaxies appear to have lower [Ca/Fe] and [Ti/Fe] than[Mg/Fe] ratios, unlike similar metallicity stars in the Galaxy.Predictions from the α-process (α-rich freeze-out) would beconsistent with this result if there have been a lack of hypernovae indSph galaxies. The α-process could also be responsible for thevery low Y abundances in the metal-poor stars in dSph's; since [La/Eu](and possibly [Ba/Eu]) are consistent with pure r-process results, thelow [Y/Eu] suggests a separate r-process site for this light(first-peak) r-process element. We also discuss SNe II rates and yieldsas other alternatives, however. In stars with higher metallicities([Fe/H]>=-1.8), contributions from the s-process are expected; [(Y,La, and Ba)/Eu] all rise as expected, and yet [Ba/Y] is still muchhigher in the dSph stars than similar metallicity Galactic stars. Thisresult is consistent with s-process contributions from lower metallicityAGB stars in dSph galaxies, and is in good agreement with the slowerchemical evolution expected in the low-mass dSph galaxies relative tothe Galaxy, such that the build-up of metals occurs over much longertimescales. Future investigations of nucleosynthetic constraints (aswell as galaxy formation and evolution) will require an examination ofmany stars within individual dwarf galaxies.Finally, the Na-Ni trend reported in 1997 by Nissen & Schuster isconfirmed in Galactic halo stars, but we discuss this in terms of thegeneral nucleosynthesis of neutron-rich elements. We do not confirm thatthe Na-Ni trend is related to the accretion of dSph galaxies in theGalactic halo.

Cu and Zn in the early Galaxy
We present Cu and Zn abundances for 38 FGK stars, mostly dwarfs,spanning a metallicity range between solar and [Fe/H] = -3. Theabundances were obtained using Kurucz's local thermal equilibrium (LTE)model atmospheres and the near-UV lines of Cu I 3273.95 Å and Zn I3302.58 Å observed at high spectral resolution. The trend of[Cu/Fe] versus [Fe/H] is almost solar for [Fe/H] > -1 and thendecreases to a plateau <[Cu/Fe]> = -0.98 at [Fe/H] < -2.5,whereas the [Zn/Fe] trend is essentially solar for [Fe/H] > -2 andthen slightly increases at lower metallicities to an average value of<[Zn/Fe]> = +0.18. We compare our results with previous work onthese elements, and briefly discuss them in terms of nucleosynthesisprocesses. Predictions of halo chemical evolution fairly reproduce thetrends, especially the [Cu/Fe] plateau at very low metallicities, but toa lesser extent the higher [Zn/Fe] ratios at low metallicities,indicating possibly missing yields.

Galactic evolution of nitrogen
We present detailed spectroscopic analysis of nitrogen abundances in 31unevolved metal-poor stars analysed by spectral synthesis of the near-UVNH band at 3360 Å observed at high resolution with varioustelescopes. We found that [N/Fe] scales with that of iron in themetallicity range -3.1 <[Fe/H]<0 with the slope 0.01±0.02.Furthermore, we derive uniform and accurate (N/O) ratios using oxygenabundances from near-UV OH lines obtained in our previous studies. Wefind that a primary component of nitrogen is required to explain theobservations. The NH lines are discovered in the VLT/UVES spectra of thevery metal-poor subdwarfs G64-12 and LP815-43 indicating that thesestars are N rich. The results are compared with theoretical models andobservations of extragalactic H II regions and Damped Lyα systems.This is the first direct comparison of the (N/O) ratios in these objectswith those in Galactic stars.

The Geneva-Copenhagen survey of the Solar neighbourhood. Ages, metallicities, and kinematic properties of ˜14 000 F and G dwarfs
We present and discuss new determinations of metallicity, rotation, age,kinematics, and Galactic orbits for a complete, magnitude-limited, andkinematically unbiased sample of 16 682 nearby F and G dwarf stars. Our˜63 000 new, accurate radial-velocity observations for nearly 13 500stars allow identification of most of the binary stars in the sampleand, together with published uvbyβ photometry, Hipparcosparallaxes, Tycho-2 proper motions, and a few earlier radial velocities,complete the kinematic information for 14 139 stars. These high-qualityvelocity data are supplemented by effective temperatures andmetallicities newly derived from recent and/or revised calibrations. Theremaining stars either lack Hipparcos data or have fast rotation. Amajor effort has been devoted to the determination of new isochrone agesfor all stars for which this is possible. Particular attention has beengiven to a realistic treatment of statistical biases and errorestimates, as standard techniques tend to underestimate these effectsand introduce spurious features in the age distributions. Our ages agreewell with those by Edvardsson et al. (\cite{edv93}), despite severalastrophysical and computational improvements since then. We demonstrate,however, how strong observational and theoretical biases cause thedistribution of the observed ages to be very different from that of thetrue age distribution of the sample. Among the many basic relations ofthe Galactic disk that can be reinvestigated from the data presentedhere, we revisit the metallicity distribution of the G dwarfs and theage-metallicity, age-velocity, and metallicity-velocity relations of theSolar neighbourhood. Our first results confirm the lack of metal-poor Gdwarfs relative to closed-box model predictions (the ``G dwarfproblem''), the existence of radial metallicity gradients in the disk,the small change in mean metallicity of the thin disk since itsformation and the substantial scatter in metallicity at all ages, andthe continuing kinematic heating of the thin disk with an efficiencyconsistent with that expected for a combination of spiral arms and giantmolecular clouds. Distinct features in the distribution of the Vcomponent of the space motion are extended in age and metallicity,corresponding to the effects of stochastic spiral waves rather thanclassical moving groups, and may complicate the identification ofthick-disk stars from kinematic criteria. More advanced analyses of thisrich material will require careful simulations of the selection criteriafor the sample and the distribution of observational errors.Based on observations made with the Danish 1.5-m telescope at ESO, LaSilla, Chile, and with the Swiss 1-m telescope at Observatoire deHaute-Provence, France.Complete Tables 1 and 2 are only available in electronic form at the CDSvia anonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/418/989

Empirically Constrained Color-Temperature Relations. II. uvby
A new grid of theoretical color indices for the Strömgren uvbyphotometric system has been derived from MARCS model atmospheres and SSGsynthetic spectra for cool dwarf and giant stars having-3.0<=[Fe/H]<=+0.5 and 3000<=Teff<=8000 K. Atwarmer temperatures (i.e., 8000-2.0. To overcome thisproblem, the theoretical indices at intermediate and high metallicitieshave been corrected using a set of color calibrations based on fieldstars having well-determined distances from Hipparcos, accurateTeff estimates from the infrared flux method, andspectroscopic [Fe/H] values. In contrast with Paper I, star clustersplayed only a minor role in this analysis in that they provided asupplementary constraint on the color corrections for cool dwarf starswith Teff<=5500 K. They were mainly used to test thecolor-Teff relations and, encouragingly, isochrones thatemploy the transformations derived in this study are able to reproducethe observed CMDs (involving u-v, v-b, and b-y colors) for a number ofopen and globular clusters (including M67, the Hyades, and 47 Tuc)rather well. Moreover, our interpretations of such data are verysimilar, if not identical, with those given in Paper I from aconsideration of BV(RI)C observations for the sameclusters-which provides a compelling argument in support of thecolor-Teff relations that are reported in both studies. Inthe present investigation, we have also analyzed the observedStrömgren photometry for the classic Population II subdwarfs,compared our ``final'' (b-y)-Teff relationship with thosederived empirically in a number of recent studies and examined in somedetail the dependence of the m1 index on [Fe/H].Based, in part, on observations made with the Nordic Optical Telescope,operated jointly on the island of La Palma by Denmark, Finland, Iceland,Norway, and Sweden, in the Spanish Observatorio del Roque de losMuchachos of the Instituto de Astrofisica de Canarias.Based, in part, on observations obtained with the Danish 1.54 mtelescope at the European Southern Observatory, La Silla, Chile.

Oxygen line formation in late-F through early-K disk/halo stars. Infrared O I triplet and [O I] lines
In order to investigate the formation of O I 7771-5 and [O I] 6300/6363lines, extensive non-LTE calculations for neutral atomic oxygen werecarried out for wide ranges of model atmosphere parameters, which areapplicable to early-K through late-F halo/disk stars of variousevolutionary stages.The formation of the triplet O I lines was found to be well described bythe classical two-level-atom scattering model, and the non-LTEcorrection is practically determined by the parameters of theline-transition itself without any significant relevance to the detailsof the oxygen atomic model. This simplifies the problem in the sensethat the non-LTE abundance correction is essentially determined only bythe line-strength (Wlambda ), if the atmospheric parametersof Teff, log g, and xi are given, without any explicitdependence of the metallicity; thus allowing a useful analytical formulawith tabulated numerical coefficients. On the other hand, ourcalculations lead to the robust conclusion that LTE is totally valid forthe forbidden [O I] lines.An extensive reanalysis of published equivalent-width data of O I 7771-5and [O I] 6300/6363 taken from various literature resulted in theconclusion that, while a reasonable consistency of O I and [O I]abundances was observed for disk stars (-1 <~ [Fe/H] <~ 0), theexistence of a systematic abundance discrepancy was confirmed between OI and [O I] lines in conspicuously metal-poor halo stars (-3 <~[Fe/H] <~ -1) without being removed by our non-LTE corrections, i.e.,the former being larger by ~ 0.3 dex at -3 <~ [Fe/H] <~ -2.An inspection of the parameter-dependence of this discordance indicatesthat the extent of the discrepancy tends to be comparatively lessenedfor higher Teff/log g stars, suggesting the preference ofdwarf (or subgiant) stars for studying the oxygen abundances ofmetal-poor stars.Tables 2, 5, and 7 are only available in electronic form, at the CDS viaanonymous ftp to cdsarc.u-strasbg.fr (130.79.128.5) or viahttp://cdsweb.u-strasbg.fr/cgi-bin/qcat?J/A+A/402/343 and Table\ref{tab3} is only available in electronic form athttp://www.edpsciences.org

Improved Astrometry and Photometry for the Luyten Catalog. II. Faint Stars and the Revised Catalog
We complete construction of a catalog containing improved astrometry andnew optical/infrared photometry for the vast majority of NLTT starslying in the overlap of regions covered by POSS I and by the secondincremental Two Micron All Sky Survey (2MASS) release, approximately 44%of the sky. The epoch 2000 positions are typically accurate to 130 mas,the proper motions to 5.5 mas yr-1, and the V-J colors to0.25 mag. Relative proper motions of binary components are measured to 3mas yr-1. The false-identification rate is ~1% for11<~V<~18 and substantially less at brighter magnitudes. Theseimprovements permit the construction of a reduced proper-motion diagramthat, for the first time, allows one to classify NLTT stars intomain-sequence (MS) stars, subdwarfs (SDs), and white dwarfs (WDs). We inturn use this diagram to analyze the properties of both our catalog andthe NLTT catalog on which it is based. In sharp contrast to popularbelief, we find that NLTT incompleteness in the plane is almostcompletely concentrated in MS stars, and that SDs and WDs are detectedalmost uniformly over the sky δ>-33deg. Our catalogwill therefore provide a powerful tool to probe these populationsstatistically, as well as to reliably identify individual SDs and WDs.

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